Durable water repellent and coated articles
AssigneeDaikin Industries, Ltd.
InventorsSusumu Wada, Kayoko Honda, Keiko Kunimasa, Katsuhiko Imoto
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Abstract
A durable water repellent agent comprising a repellent and a fluorine-containing resin, wherein the repellent comprises at least one member selected from the group consisting of a perfluoroalkyl group-containing substance (I), a fluorine-containing surfactant (II), a fluorine-containing oil (III), a fluorosilicone oil (IV) and a silicone oil (V), the solid content weight ratio between said repellent and said fluorine-containing resin being (repellent):(fluorine-containing resin)=50:50 to 99:1.
Claims10
A durable water repellent agent comprising a repellent and a fluorine-containing resin, wherein the repellent comprises a perfluoroalkyl group-containing polymer, the solid content weight ratio between said repellent and said fluorine-containing resin being (repellent):(fluorine-containing resin)=50:50 to 99:1,
- said perflouroalkyl group-containing polymer comprises a copolymer of a perfluoroalkyl group-containing ethylenically unsaturated monomer and one or more other monomers,
- said perfluoroalkyl group-containing ethylenically unsaturated monomer is at least one compound selected from the group consisting of:
- in the formulas, Rf represents a perfluoroalkyl group whose alkyl moiety contains 4 to 20 carbon atoms, R1 represents hydrogen or an alkyl group containing 1 to 10 carbon atoms, R2 represents an alkylene group containing 1 to 10 carbon atoms, R3 represents hydrogen or a methyl group, R4 represents an alkyl group containing 1 to 17 carbon atoms, n represents an integer of 1 to 10 and m represents an integer of 0 to 10,
- said other monomers are selected from the group consisting of alkyl(meth)acrylates containing 1 to 20 carbon atoms in the alkyl moiety, cyclohexyl(meth)acrylate, benzyl(meth)acrylate, polyethylene glycol di(meth)acrylate, N-methylolacrylamide, ethylene, vinyl chloride, (meth)acrylamide, styrene, α-methylstyrene, p-methylstyrene, vinyl alkyl ethers containing 1 to 20 carbon atoms in the alkyl moiety, halogenated alkyl vinyl ethers containing 1 to 20 carbon atoms in the alkyl moiety, vinyl alkyl ketones containing 1 to 20 carbon atoms in the alkyl moiety, maleic anhydride,
- butadiene, isoprene, chloroprene and silyl-containing vinyl monomers,
- said fluorine-containing resin comprises a fluororesin or a mixture of a fluororesin and some other resin,
- said fluororesin comprises a copolymer of a fluoroolefin and a vinyl monomer or a copolymer of fluoroolefins, or is obtained by seed polymerization of an acrylic resin.
Dependencies are inferred from the claim text.