Epoxy resin composition, cured article thereof, novel epoxy resin, novel phenol compound, and process for preparing the same
AssigneeDainippon Ink and Chemicals, Inc.
InventorsIchiro Ogura, Yoshiyuki Takahashi, Tomoyuki Imada
Life of this patent
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Abstract
The present invention relates to an epoxy resin composition a cure article thereof, a novel epoxy resin used therein, a polyhydric phenol compound suited for used as an intermediate thereof, and a process for preparing the same. One of the objects to be achieved by the present invention is to exert the heat resistance, the moisture resistance, the dielectric performances and the flame-resistant effect required of electric or electronic materials such as semiconductor encapsulating materials and varnishes for circuit boards in the epoxy resin composition.
Claims18
An epoxy resin composition comprising an epoxy resin and a curing agent, wherein the epoxy resin has an aromatic polycyclic structure having a methyl group in which two aromatic hydrocarbons are bonded through carbon atoms or oxygen atoms in two adjacent substitution positions on an aromatic ring in the aromatic hydrocarbon, and also has glycidyloxy groups as a substituent on the aromatic polycyclic structure as well.
An epoxy resin composition comprising an epoxy resin and a curing agent, wherein the epoxy resin has a chemical structure represented by the following general formula (2):
- in the general formula (2), X represents oxygen atom, a methylene group, a methylene group substituted with an alkyl group having 1 to 4 carbon atoms, a methylene group substituted with a phenyl group, a methylene group substituted with a naphthyl group, a methylene group substituted with a biphenyl group, a methylene group substituted with a 9-fluorenyl group, or a methylene group in which an alkyl group is further aromatic nucleus-substituted on the phenyl group, the naphthyl group or the biphenyl group, n and m represents an integer of 0 to 5, and p represents an average repeated unit number of 0 to 10.
A novel epoxy resin represented by the general formula (1):
- in the general formula (1), X represents oxygen atom, a methylene group, a methylene group substituted with an alkyl group having 1 to 4 carbon atoms, a methylene group substituted with a phenyl group, a methylene group substituted with a naphthyl group, a methylene group substituted with a biphenyl group, a methylene group substituted with a 9-fluorenyl group, or a methylene group in which an alkyl group is further aromatic nucleus-substituted on the phenyl group, the naphthyl group or the biphenyl group, n and m represent an integer of 1 to 3, and p represents an average repeated unit number of 0 to 10.
A novel epoxy resin represented by the general formula (2):
- in the general formula (2), X represents oxygen atom, a methylene group, a methylene group substituted with an alkyl group having 1 to 4 carbon atoms, a methylene group substituted with a phenyl group, a methylene group substituted with a naphthyl group, a methylene group substituted with a biphenyl group, a methylene group substituted with a 9-fluorenyl group, or a methylene group in which an alkyl group is further aromatic nucleus-substituted on the phenyl group, the naphthyl group or the biphenyl group, n and m represents an integer of 0 to 5, and p represents an average repeated unit number of 0 to 10.
A novel phenol compound represented by the general formula (4):
- in the general formula (4), X represents oxygen atom, a methylene group, a methylene group substituted with an alkyl group, a methylene group substituted with a phenyl group, a methylene group substituted with a naphthyl group, a methylene group substituted with a biphenyl group, a methylene group substituted with a 9-fluorenyl group, or a methylene group in which an alkyl group is further aromatic nucleus-substituted on the phenyl group, the naphthyl group or the biphenyl group, and n and m represent an integer of 0 to 5.
A process for preparing a polyhydric hydroxy compound, which comprises reacting a compound having two hydroxyl groups on the benzene ring, one of the hydroxyl groups having a hydrogen atom at the ortho-position and a substituent at all of other substitution positions, with a carbonyl group-containing compound in the presence of an acid catalyst.
A process for preparing a polyhydric hydroxyl compound, which comprises reacting a dihydroxynaphthalene having hydrogen atoms at the position adjacent to hydroxyl groups with a carbonyl group-containing compound in the presence of an acid catalyst.
A process for preparing an epoxy resin, which comprises:
- Step 1:
- reacting a dihydroxynaphthalene having hydrogen atoms at the position adjacent to hydroxyl group with a carbonyl group-containing compound in the presence of an acid catalyst, and
- Step 2:
- reacting the obtained compound with an epihalohydrin.
Dependencies are inferred from the claim text.