Halogenated optical polymer composition
AssigneeE. I. Du Pont de Nemours and Company
InventorRobert M. Blomquist
Life of this patent
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Abstract
The invention provides polymeric optical materials that can be cured in air and have low optical loss in both the C-band and the L-band of the telecommunications spectrum. The polymeric materials are made by the free radical polymerization of an at least difunctional thiol compound with an at least difunctional ethylenically unsaturated compound wherein at least one of the thiol compound and the ethylenically unsaturated compound is at least partially halogenated. The compositions of this invention may be used to fabricate planar optical waveguides with low loss and low birefringence.
Claims10
An optical element comprising a polymeric core including a polymeric material including thioether moieties in a concentration of at least 0.05 M and at least one at least partially halogenated moiety;
- wherein the optical element comprises
- a polymeric overclad layer;
- a polymeric cladding layer;
- and
- a substrate
- wherein the polymeric core is contiguous on at least one side with the polymeric overclad layer, and contiguous on at least one side with the polymeric cladding layer;
- and the polymeric cladding layer is between the polymeric core and the substrate wherein the halogenated moiety is selected from the group consisting of
- —(CF2)x—,
- —(CF3)2C—,
- —CF2O—[(CF2CF2O)m(CF2O)n]—CF2—,
- —CF(CF3)O(CF2)4O[CF(CF3)CF2O]pCF(CF3)—, and
- —CF2O—(CF2CF2O)m—CF2—,
- wherein x is an integer between 1 and about 10;
- m and n designate the number of randomly distributed perfluoroethyleneoxy and perfluoromethyleneoxy backbone repeating subunits, respectively;
- and
- p designates the number of —CF(CF3)CF2O— backbone repeating subunits.
An optical element comprising a polymeric core including a polymeric material including thioether moieties in a concentration of at least 0.05 M and at least one at least partially halogenated moiety wherein the polymeric material is produced from a energy curable composition comprising the compound
- wherein m and n designate the number of randomly distributed perfluoroethyleneoxy and perfluoromethyleneoxy backbone repeating subunits, respectively, and the ratio of m:n is between about 0.5:1 and about 1.4:1.
An optical element comprising a polymeric core including a polymeric material including thioether moieties in a concentration of at least 0.05 M and at least one at least partially halogenated moiety wherein the polymeric material is produced from an energy curable composition comprising the compound
- CH2═CHCO2CH2CF2O(CF2CF2O)m(CF2O)nCF2CH2O2CCH═CH2
- wherein m and n designate the number of randomly distributed perfluoroethyleneoxy and perfluoromethyleneoxy backbone repeating subunits, respectively, and the ratio of m:n is between about 0.5:1 and about 1.4:1.
A method of making an optical element comprising the steps of:
- (a) applying a layer of a clad composition to a substrate, the clad composition including an at least difunctional thiol compound, an at least difunctional ethylenically unsaturated compound, and a selected amount of a free radical initiator
- wherein at least one of the thiol compound and the ethylenically unsaturated compound is at least partially halogenated,
- the ratio of thiol moieties to isolated ethylenically unsaturated moieties is between about 1:2 and about 2:1 and
- the ethylenically unsaturated compound account for between about 35% and about 99.9% of the cladding composition;
- (b) at least partially curing the cladding composition to form a polymeric cladding layer;
- (c) applying a photosensitive core composition to the surface of the polymeric cladding layer to form a core composition layer, the core composition including an at least difunctional thiol compound, an at least difunctional ethylenically unsaturated compound, and a selected amount of a free radical initiator
- wherein at least one of the thiol compound and the ethylenically unsaturated compound is at least partially halogenated,
- the ratio of thiol moieties to isolated ethylenically unsaturated moieties is between about 1:2 and about 2:1 and
- the ethylenically unsaturated compound accounts for between about 35% and about 99.9% of the core composition;
- (d) imagewise exposing the photosensitive core composition layer to sufficient actinic radiation to effect the at least partial polymerization of an imaged portion and to form at least one non-imaged portion of the photosensitive core composition layer;
- (e) removing the at least one non-imaged portion without removing the imaged portion, thereby forming a polymeric patterned core from the imaged portion;
- (f) applying a photosensitive overclad composition onto the polymeric patterned core;
- and
- (g) at least partially curing the overclad composition to form a polymeric overclad layer,
- wherein the polymeric overclad layer and the polymeric cladding layer have a lower refractive index than the polymeric patterned core.
Dependencies are inferred from the claim text.