# US 6,778,378 B1 · Flow-through capacitor and method

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- Number: US 6,778,378 B1
- Document ID: US6778378B1
- Status: Granted
- Kind: B1
- Application number: 10/048,632
- Filed: 2002-01-30
- Granted: 2004-08-17
- Earliest claimed: 1999-07-30
- Assignees: Biosource, Inc.
- Inventors: Marc D. Andelman
- Web page: https://patentgrep.com/patent/US6778378B1

## CPC

- C02F 1/46109: {Electrodes}
- C02F 1/4691: {Capacitive deionisation}
- C02F 2001/46161: {Porous electrodes}
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)

## Abstract

A flow-through capacitor and method for the purification of fluids, like soft water. The capacitor includes anode-cathode electrodes (3) composed of a low surface area electrode material having a surface area between 10 to 1000 square meter per gram BET (Brunauer Emmett Teller method) to form one or more cells.

## Claims

### Claim 1

A flow-through capacitor comprising:
a) a housing comprising an inlet for the introduction of a fluid and an outlet for the withdrawal of a fluid; and
b) a plurality of anode-cathode electrode layers to form a cell within the housing, the electrode layers comprising an electrode material having a capacitance of above about 1 farad per gram capacitance, the layers arranged and constructed to provide for the flow of the fluid between the layers and through the cell;
wherein the flow-through capacitor has a series resistance per individual cell of about 0.03 ohms or less.

### Claim 2 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material has a surface area of between about 10 and 1000 square meters per gram BET (Brunauer Emmett Teller method).

### Claim 3 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material has a surface area of between about 100 to 1000 square meters per gram BET (Brunauer Emmett Teller method).

### Claim 4 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material has an electrical resistance of 0.01 ohms-cm or less and a capacitance of above 10 farads per gram.

### Claim 5 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material is selected from the group consisting of carbon black, aerogel, activated carbon, carbon cloth, or combinations thereof.

### Claim 6 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material has a surface area of between about 10 and 400 square meters per gram BET (Brunauer Emmett Teller method).

### Claim 7 (depends on 1)

The flow-through capacitor of claim 1, wherein the flow-through capacitor is in electrical contact with an electrical power supply, and the resistive voltage drop from the power supply to the capacitor to less than about 4 volts.

### Claim 8 (depends on 1)

The flow-through capacitor of claim 1, whereby the anode-cathode electrodes are electrically connected in series.

### Claim 9 (depends on 1)

The flow-through capacitor of claim 1, wherein the capacitor comprises a plurality (n) of cells.

### Claim 10 (depends on 9)

The flow-through capacitor of claim 9, wherein at least a portion of the plurality (n) of individual cells is connected in series, and the operating voltage of the individual cells is 1/n of the voltage of the entire series.

### Claim 11 (depends on 1)

The flow-through capacitor of claim 1, further comprising means for measuring the voltage of an individual cell.

### Claim 12 (depends on 1)

The flow-through capacitor of claim 1, wherein the capacitor is characterized by a fluid flow rate of greater than about 1 milliliter per minute per gram (1 ml/minute/gm) of electrode material.

### Claim 13 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material is selected from the group consisting of ruthenium oxide and a fibrillated fluorocarbon, ruthenium oxide coated on titanium, tantalum and graphite material, and combinations thereof.

### Claim 14 (depends on 1)

The flow-through capacitor of claim 1, which comprises a compressed stack of electrode layers.

### Claim 15 (depends on 1)

The flow-through capacitor of claim 1, wherein said inlet fluid is a source of contaminated water, and said outlet fluid is substantially purified water.

### Claim 16 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode layers are characterized by a generally central, flow-through fluid hole.

### Claim 17 (depends on 1)

The flow-through capacitor of claim 1, wherein the electrode material has a density of 0.1 grams per cubic centimeter or higher.

### Claim 18

A method for the purification of water containing ionic contaminants, which method comprises the steps of:
a) providing the flow-through capacitor of claims
b) introducing water to be purified into the inlet; and
c) withdrawing substantially purified water from the outlet.

### Claim 19 (depends on 18)

The method of claim 18, further comprising the steps of removing ionic contaminants from the capacitor.
