Process for the production of sulfur
AssigneeMonsanto Enviro-Chem Systems, Inc.
InventorsBrian M. Burmaster, B. Gene Goar
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AssigneeMonsanto Enviro-Chem Systems, Inc.
InventorsBrian M. Burmaster, B. Gene Goar
Estimating the term…
A process is provided for producing elemental sulfur from hydrogen sulfide contained in an acid gas feed stream wherein hydrogen sulfide and sulfur dioxide are reacted in a catalytic only sulfur recovery unit comprising a single catalytic converter containing a Claus catalytic reaction zone. A sulfur dioxide-enriched gas recovered from tail gas treatment is recycled and introduced into the catalytic reaction zone as part of a feed gas mixture that also includes the acid gas feed stream. Temperatures within the catalytic reaction zone are effectively moderated by recycle of tail gas effluent to the converter so that high concentrations of hydrogen sulfide in the acid gas feed stream can be tolerated and improved process flexibility and capacity are realized. A pretreatment process including contacting the acid gas with an aqueous acid wash to reduce the concentration of unsaturated hydrocarbons in the acid gas and inhibit deactivation of the oxidation catalyst is also disclosed.
A process for the production of elemental sulfur from an acid gas feed stream containing hydrogen sulfide, the process comprising the steps of:
The process as set forth in 27 wherein the addition reaction product separated from the acid gas feed stream is introduced into the combustion zone.
A process for the production of elemental sulfur from an acid gas feed stream containing hydrogen sulfide and an unsaturated hydrocarbon component selected from the group consisting of linear olefins, branched olefins, aromatic hydrocarbons and mixtures thereof, the process comprising oxidizing hydrogen sulfide from the acid gas feed stream to elemental sulfur in a catalytic reaction zone containing an oxidation catalyst and supplied with an oxidant gas, wherein the improvement comprises pretreating the acid gas feed stream upstream of the catalytic reaction zone to reduce the concentration of the unsaturated hydrocarbon component and inhibit deactivation of the oxidation catalyst, pretreatment of the acid gas feed stream comprising:
Dependencies are inferred from the claim text.