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US 6,743,901 B1Granted
Preparation of liquid formulations of basic azo dyes
AssigneeBASF SE
InventorsMichael Schmitt, Roland Merger, Rainer Tresch
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Abstract
A process for preparing liquid formulations of dyes of the general formula I where the variables are as defined in the specification by diazotizing an amine of the formula II and then coupling the diazonium salt onto a compound of the formula III and also optionally adding solubilizing additives, which comprises effecting said diazotizing at a pH set to an acidic value using pure methanesulfonic acid or at least 20 mol % mixtures of methanesulfonic acid in monobasic acids.
Claims8
A process for preparing liquid formulations of dyes of the general formula I
- where
- Y is chlorine or bromine,
- Z is hydrogen, chlorine, bromine, sulfonic ester, nitro or optionally substituted sulfamoyl,
- R is alkylene optionally interrupted by oxygen,
- m is 1 or 2,
- n is 0 or 1,
- p is 0, 1 or 2,
- An⊖ is the equivalent of an anion,
- R1 and R2 are independently hydrogen, optionally substituted alkyl, alkenyl, cycloalkyl, aralkyl or aryl or cominbe with the joining nitrogen to form a heterocycle,
- R3 is hydrogen or optionally substituted alkyl,
- B is hydrogen or C1- to C4-alkyl,
- B1 is hydrogen, hydroxyl, C1- to C4-alkoxy or C1- to C4-alkyl, where
- R4 is optionally substituted alkyl and
- R5 is hydrogen or C1- to C4-alkyl, and the radical
- may also be an optionally substituted piperazine radical, by diazotizing an amine of the formula II
- and then coupling the diazonium salt onto a compound of the formula III
- and also optionally adding solubilizing additives, which comprises effecting said diazotizing at a pH set to an acidic value using pure methanesulfonic acid or at least 20 mol % mixtures of methanesulfonic acid in monobasic acids.
14 more elements
Dependencies are inferred from the claim text.