Single-shot differential spectroscopy and spectral-imaging at submillimeter wavelengths
AssigneeImra America, Inc.
InventorsGregg D. Sucha, Donald J. Harter, Almantas Galvanauskas
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Abstract
An invention is described, which uses terahertz radiation for chemical sensing and gas analysis. Relatively narrow-band THz radiation is generated by impinging an optical pulse train from a short-pulse laser source on a THz emitter. Coherent detection of the resulting THz radiation is accomplished by using a similar optical pulse train to activate the THz sensor. The invention is shown to detect and indicate various concentrations of water vapor in air. Optimal phase biasing conditions give maximum sensitivity to variations in concentration of the species under investigation.
Claims26
An apparatus, for generating narrowband THz waveforms, comprising:
- an ultrashort pulse laser;
- a pulse-shaping device which receives an output of said ultrashort pulse laser and generates an optical pulse train at an optical wavelength different from a wavelength of said output;
- and
- a THz emitter which is excited by said optical pulse train.
An apparatus for coherently sensing narrowband THz waveforms, comprising:
- an ultrashort pulse laser;
- a pulse shaper which converts a single optical pulse into a THz pulse train;
- and
- a THz sensor which is activated by said pulse train.
A method for coherent detection of narrowband THz radiation comprising:
- generating a sequence of ultrashort optical pulses at a THz repetition rate;
- and
- effecting detection of the THz radiation by the sequence of ultrashort optical pulses.
A method of chemical analysis employing a narrowband THz sensing system comprising:
- generating ultrashort laser pulses;
- receiving said ultrashort laser pulses and generating an optical pulse train at an optical wavelength different from a wavelength of said ultrashort laser pulses;
- exciting a THz emitter by said optical pulse train;
- outputting said optical pulse train to the THz emitter and a narrowband THz sensor;
- and adjusting THz pulses emitted from the THz emitter with respect to an intensity envelope phase of said optical pulse train incident on the THz sensor;
- wherein the ultrashort laser pulses excite both the THz emitter and the THz sensor, and a THz beam generated by the THz emitter impinges on the THz sensor;
- said method further comprising passing the THz beam generated by the THz emitter through a sample region containing at least one chemical species, and determining a property of said chemical species from at least one of (1) analysis of said THz beam after passage through said sample region and (2) a radiation, which follows said THz beam, due to free induction decay.
An apparatus comprising:
- an ultrashort pulse laser;
- a first pulse shaper;
- a second pulse shaper separate from said first pulse shaper;
- a first THz emitter transmitting a first THz beam along a first THz beam path;
- a second THz emitter, separate from said first THz transmitter, transmitting a second THz beam along a second THz beam path, distinct from said first THz beam path;
- a first THz sensor;
- and
- a second THz sensor, separate from said first THz sensor,
- wherein said first THz emitter and said first THz sensor are excited by an optical pulse train from said first pulse shaper, and said second THz emitter and said second THz sensor are excited by an optical pulse train from said second pulse shaper.
A method for chemical sensing using a two-frequency THz apparatus comprising:
- an ultrashort pulse laser;
- a first pulse shaper;
- a second pulse shaper separate from said first pulse shaper;
- a first THz emitter transmitting a first THz beam along a first THz beam path;
- a second THz emitter, separate form said first THz transmitter, transmitting a second THz beam along a second THz beam path, distinct from said first THz beam path;
- a first THz sensors;
- and a second THz sensors, separate from said first THz sensor, wherein said first THz emitter and said first THz sensor are excited by an optical pulse train from said first pulse shaper, and said second THz emitter and said second THz sensor are excited by an optical pulse train from said second pulse shaper, said method comprising:
- passing THz beams generated by said first and second THz emitters through a sample region containing a chemical species
- tuning one of said first and second THz emitters to an absorption resonance of the chemical species;
- and
- tuning another of said first and second THz emitters away from any absorption resonance of the chemical species,
- detecting the signals from each of the two THz sensors, and measuring the difference or normalized difference between the signals, and determining a property of the chemical species in said sample from said difference.
An apparatus for imaging narrowband THz radiation comprising:
- an ultrashort pulse laser;
- a pulse-shaping frequency converter which receives an output of said ultrashort pulse laser and generates a pulse train at an optical wavelength different from a wavelength of said output;
- a narrowband THz emitter which is excited by said optical pulse train;
- a THz field sensor;
- polarization optics which modify the polarization properties of the pulse train after the pulse train passes through the THz field sensor;
- and
- an imaging device.
An apparatus for generation of frequency-converted pulse sequences from a single input pulse, said apparatus comprising a tunable quasi-phase-matched nonlinear optical device in which:
- a tunability of a pulse repetition frequency is designed into a structure of said tunable quasi-phase-matched nonlinear optical device by a lateral variation in spacing between poled regions of said tunable quasi-phase-matched nonlinear optical device, and
- a tunability of a pulse repetition frequency is effected by laterally positioning an input pulse to propagate along one of a plurality of the poled regions.
A method of chemical analysis comprising:
- generating ultrashort wavelength laser pulses;
- generating an optical pulse train at an optical wavelength different from a wavelength of said ultrashort wavelength laser pulses;
- exciting an emitter by said optical pulse train;
- passing said optical pulse train excited by said emitter through a sample region containing at least one chemical species;
- and
- determining a property of said chemical species from analysis of at least one of (1) said beam passed through said sample region, and (2) a radiation, which follows said beam, due to free induction decay.
Dependencies are inferred from the claim text.