Metal complex containing one or more silsesquioxane ligands
AssigneeDsm N.V.
InventorsMaurits F. H. Van Tol, Sven K. H. Thiele, Robbert Duchateau, Hendrikus C. L. Abbenhuis, Rutger A. Van Santen
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AssigneeDsm N.V.
InventorsMaurits F. H. Van Tol, Sven K. H. Thiele, Robbert Duchateau, Hendrikus C. L. Abbenhuis, Rutger A. Van Santen
Estimating the term…
Metal complex containing one or more silsesquioxane ligands having the formula: Zy(MAx)b (I) wherein Z is a silsesquioxane ligand according to the formula: (RSiO1.5)mOnBq (II) which is connected within one corner to one atom M or to two atoms M by one bridging oxygen atom, M is a metal from groups 3-10 of the Periodic System of the Elements and the lanthanides, A is a substituent bonded to the metal, y represents the number of silsesquioxane ligands and is 2-10, b represents the number of metal groups and is 2-20, x is the number of substituents A bonded to the metal; the value of x depends on the metal used and is equal to the valency of the metal minus 1, 2, 3 or 4, R is a substituent bonded to each Si, m is an integer and is equal to 5-19, n is 1.5 or 3, B is a group bonded to an oxygen atom that has one bond to Si and q is 0, 1 or 2.
Process for the polymerization of olefins, comprising contacting the olefin with a metal complex having the formula Zy(MAx)b, wherein
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