Supported olefin polymerization catalyst composition
AssigneeBorealis Technology Oy
InventorsKalle Kallio, Marja Mustonen, Hilkka Knuuttila
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Abstract
Alumoxanes having C2-C12 alkyl groups can conveniently be used in supported olefin polymerization catalyst compositions prepared by contacting, either previous to or immediately before the beginning of the olefin polymerization, a support comprising a porous carrier with (a) an organometallic compound of the general formula R1MXv−1, (b) a metallocene of the general formula (CpY)mM′X′nZo and an alumoxane of the following general formula in any order.
Claims38
A process for the preparation of a supported olefin polymerization catalyst composition, comprising a support, a metallocene, and an alumoxane, wherein a support comprising a porous carrier is contacted, in any order, with at least one member of the group consisting of
- (a) an organometallic compound of the general formula (1):
- R1MXv−1 (1)
- wherein each R is the same or different and is a C1-C10 alkyl group;
- M is a metal of Group 1, 2, 12 or 13 of the Periodic Table;
- each X is the same or different and one of a halogen atom, a hydrogen atom, a hydroxyl radical or a C1-C8 hydrocarbyloxy group;
- I is 1, 2 or 3;
- v is the oxidation number of the metal M,
- and with a complex solution of at least
- (b) a metallocene of the general formula (2):
- (CpY)mM′X′nZo
- wherein each CpY is the same or different and is one of a mono- or polysubstituted, fused or non-fused, homo- or heterocyclic cyclopentadienyl, indenyl, tetrahydro-indenyl, fluorenyl, or octahydrofluorenyl ligand, which ligand is substituted at its cyclopentadienyl ring with at least one substituent Y which is one of a —OR′, —SR′, —NR′2, or —PR′2 radical, each R′ being the same or different and is one of a tri-C1-C8 hydrocarbylsilyl group or a tri-C1-C8 hydrocarbyloxy silyl group;
- M′ is a transition metal of Group 4 of the Periodic Table and bound to the ligand CpY at least in an N5 bonding mode;
- each X′ is the same or different and is one of a hydrogen atom, a halogen atom, a C1-C8 hydrocarbyl group, a C1-C8 hydrocarbylheteroatom group or a tri-C1-C8 hydrocarbyl silyl group or two X′ form a ring with each other;
- Z is a bridge atom or group between two CpY ligands, or one CpY ligand and the transition metal M′;
- m is 1 or 2;
- o is 0 or 1′ and n is 4-m if there is no bridge Z or Z is a bridge between two CpY ligands, or n is 4-m-o if Z is a bridge between one CpY ligand and the transition metal M′, and
- (c) an alumoxane of one of the following formulas (3):
- wherein each R″ and each R′″ is the same or different and is a C2-C12 alkyl group;
- and p is an integer between 1 and 40;
- and recovering said supported olefin polymerization catalyst composition.
Dependencies are inferred from the claim text.