# US 6,719,423 B2 · Ink jet process including removal of excess liquid from an intermediate member > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 6,719,423 B2 - Document ID: US6719423B2 - Status: Granted - Kind: B2 - Application number: 09/973,239 - Filed: 2001-10-09 - Published: 2003-04-10 - Granted: 2004-04-13 - Earliest claimed: 2001-10-09 - Assignees: NexPress Solutions LLC - Inventors: Arun Chowdry; Thomas Nathaniel Tombs; John Walter May - Web page: https://patentgrep.com/patent/US6719423B2 ## CPC - B41J 2/04: generating single droplets or particles on demand - B41J 2/17: characterised by ink handling {(cleaning by driving a fluid through the nozzles to the outside thereof B41J2/1652; for treating before, during or after printing or for uniform coating or laminating the copy material before or after printing B41J11/0015)} - B41M 5/0256: {the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means} - B41J 2002/012: {with intermediate transfer member} - B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS - B41M: PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING, (correction of typographical errors B41J; processes for applying transfer pictures or the like B44C1/16; fluid media for correction of typographical errors by coating C09D10/00; printing textiles D06P) ## Abstract Apparatus and method of making an ink-jet-ink-derived material image on a receiver. An ink jet device is used to form a colloidal ink image on a member. The ink for use in the ink jet device includes an aqueous-based colloidal dispersion of particles and a nonaqueous colloidal dispersion of particles. The ink for use in the ink jet device includes an aqueous-based colloidal dispersion of particles, a nonaqueous colloidal dispersion of particles. The particles of the colloidal ink image are caused to become concentrated adjacent an operational surface of the member. Excess liquid is removed from the particles so as to form an ink-jet-ink-derived material image. The ink-jet-ink-derived image is then transferred from the operational surface of the intermediate member to another member, which another member may be a receiver member, a drum or a web. ## Claims ### Claim 1 For forming an ink-jet-ink-derived material image on an operational surface of a member and transferring said ink-jet-ink-derived material image to a receiver member, an imaging apparatus comprising: an ink jet device for imagewise jetting, on to said operational surface of said member, droplets of an ink made of particles dispersed in a carrier fluid, said ink jet device thereby forming on said operational surface a primary image, said primary image including said particles and said carrier fluid; a plurality of process zones associated with said operational surface of said member, said plurality of process zones located sequentially in proximity with said operational surface and said plurality of process zones including an image concentrating process zone, an excess liquid removal process zone, and a transfer process zone; a mechanism in said image concentrating process zone for concentrating said particles of said primary image so as to form a concentrated image on said operational surface from said primary image, said mechanism for concentrating said particles causing said particles to become concentrated adjacent said operational surface; a mechanism in said excess liquid removal process zone for removing a portion of said carrier liquid from said concentrated image so as to form on said operational surface a liquid-depleted image; a mechanism for transferring to a receiver member, from said operational surface in said transfer process zone, said liquid-depleted image; and wherein said primary image includes a plurality of smallest resolved imaging areas and each of said plurality of smallest resolved imaging areas receives from said ink jet device a preselected number of droplets of said ink, said preselected number including zero. ### Claim 2 (depends on 1) The apparatus according to claim 1, further comprising: a regeneration process zone included in said plurality of process zones, said regeneration process zone associated in proximity with said operational surface of said member at a location between said transfer zone and said ink jet device; and wherein said regeneration process zone is provided a mechanism for regenerating said operational surface, said regenerating preceding a subsequent formation by said ink jet device of a new primary image. ### Claim 3 (depends on 1) The apparatus according to claim 1 wherein said member is an intermediate member, which intermediate member is a rotatable member. ### Claim 4 (depends on 1) The apparatus according to claim 1 wherein said member is an intermediate member, which intermediate member is a linearly-movable member. ### Claim 5 (depends on 3) The apparatus according to claim 3 wherein said ink jet device forms on said intermediate member a half-tone primary image. ### Claim 6 (depends on 3) The apparatus according to claim 3 wherein said ink jet device forms on an intermediate member a continuous tone primary image. ### Claim 7 For forming an ink-jet-ink-derived material image on an operational surface of a member and transferring said ink-jet-ink-derived material image to a receiver member, an imaging apparatus comprising: an ink jet device for imagewise jetting, on to said operational surface, droplets of an ink made of particles dispersed in a carrier fluid, said ink jet device thereby forming on said operational surface of said member a primary image, said primary image including said particles and said carrier fluid; a plurality of process zones associated with said operational surface of said member, said plurality of process zones located sequentially in proximity with said operational surface and said plurality of process zones including an image concentration/liquid removal process zone and a transfer process zone; a mechanism in said image concentration/liquid removal process zone for concentrating said primary image while removing a portion of said carrier liquid so as to form on said operational surface a concentrated liquid-depleted image; a mechanism in said transfer process zone for transferring said concentrated liquid-depleted image from said operational surface to a receiver member, and wherein said primary image includes a plurality of smallest resolved imaging areas and each of said plurality of smallest resolved imaging areas receives from said ink jet device a preselected number of droplets of said ink, said preselected number including zero. ### Claim 8 (depends on 7) The apparatus according to claim 7, further comprising: a regeneration process zone included in said plurality of process zones, said regeneration process zone associated in proximity with said operational surface of said member at a location between said transfer zone and said ink jet device; and wherein said regeneration process zone is provided a mechanism for regenerating said operational surface, said regenerating preceding a subsequent formation by said ink jet device of a new primary image. ### Claim 9 (depends on 7) The apparatus according to claim 7 wherein said member is an intermediate member, which intermediate member is a rotatable member. ### Claim 10 (depends on 7) The apparatus according to claim 7 wherein said member is an intermediate member, which intermediate member is a linearly-movable member. ### Claim 11 (depends on 9) The apparatus according to claim 9 wherein said ink jet device forms on said intermediate member a half-tone primary image. ### Claim 12 (depends on 9) The apparatus according to claim 9 wherein said ink jet device forms on an intermediate member a continuous tone primary image. ### Claim 13 (depends on 1) The apparatus according to claim 1, wherein said mechanism for concentrating in said image concentrating process zone said particles of said primary image is a magnetic field mechanism. ### Claim 14 (depends on 1) The apparatus according to claim 1, wherein said mechanism for concentrating in said Image concentrating process zone said particles of said primary image is an electric field mechanism, which electric field mechanism includes one device selected from the following group: a corona charging device, a contacting device including an electrode, and a non-contacting device including an electrode. ### Claim 15 (depends on 14) The apparatus according to claim 14, wherein said electric field mechanism is a corona charging device which provides corona ions of a same polarity as a polarity of said particles dispersed in said carrier fluid, which ions are directed towards said primary image so as to charge said primary image. ### Claim 16 (depends on 14) The apparatus according to claim 14 wherein said electric field mechanism is an electrode which has the same polarity as a polarity of said particles dispersed in said carrier fluid. ### Claim 17 (depends on 7) The apparatus according to claim 7 wherein said mechanism for concentrating said primary image while removing a portion of said carrier liquid includes an evaporation mechanism and a blotting mechanism. ### Claim 18 (depends on 17) The apparatus according to claim 17 wherein said blotting mechanism comprises an absorbent layer, included in said intermediate member, for imbibing said carrier liquid, said absorbent layer having an outer surface including said operational surface of said intermediate member, said particles remaining on said operational surface during said imbibing. ### Claim 19 (depends on 18) The apparatus according to claim 18 wherein said intermediate member is a roller and said blotting mechanism further comprises: a source of vacuum which draws said carrier liquid through said absorbent layer into an interior chamber of said roller; a vent connected to said interior chamber of said roller; and wherein said source of vacuum further draws said carrier liquid through said vent so as to remove said carrier liquid from said interior chamber. ### Claim 20 (depends on 17) The apparatus according to claim 17 wherein said evaporation mechanism includes at least one of the mechanisms selected from the following group: an internal source of heat located within said intermediate member; a contact with a heated member, said heated member external to said intermediate member; a source of radiation absorbable by at least one of said intermediate member and a component of said ink included in said primary image; and an airflow. ### Claim 21 (depends on 1) The apparatus according to claim 1, wherein said mechanism for removing in said excess liquid removal process zone a portion of said carrier liquid from said concentrated image comprises a liquid-removal device, said liquid-removal device including at least one device selected from the following group: a squeegee roller; a squeegee blade; a contacting blotting device; a heating device; a skiving device; and an air knife device. ### Claim 22 (depends on 21) The apparatus according to claim 21, wherein said liquid-removal device further includes an electrode biased by a source of voltage, which voltage has a polarity the same as a polarity of said particles included in said concentrated image. ### Claim 23 (depends on 21) The apparatus according to claim 21, wherein said liquid removal device is a contacting blotting device which comprises an external member in contact with said intermediate member, said external member including an absorbent layer for imbibing said carrier liquid while said particles remain on said operational surface of said intermediate member during said imbibing by said external member. ### Claim 24 (depends on 23) The apparatus according to claim 23 wherein said external member of said blotting device is a roller, and said contacting blotting device further comprises: a source of vacuum which draws said carrier liquid through said absorbent layer into an interior chamber of said external member roller; a vent connected to said interior chamber of said external member roller; and wherein said source of vacuum further draws said carrier liquid through said vent so as to remove said carrier liquid from said interior chamber. ### Claim 25 (depends on 1) The apparatus according to claim 1 wherein said ink jet ink is a colloidal dispersion of particles, said particles comprising a pigment. ### Claim 26 (depends on 3) The apparatus according to claim 3 wherein said ink jet ink is a colloidal dispersion of particles, said particles comprising a pigment. ### Claim 27 (depends on 25) The apparatus according to claim 25 wherein said pigment is finely divided and dispersed in a binder. ### Claim 28 (depends on 26) The apparatus according to claim 26 wherein said pigment is finely divided and dispersed in a binder. ### Claim 29 (depends on 1) The apparatus according to claim 1 wherein said ink jet ink includes a carrier fluid, said carrier fluid being nonaqueous. ### Claim 30 (depends on 3) The apparatus according to claim 3 wherein said ink jet ink includes a carrier fluid, said carrier fluid being nonaqueous. ### Claim 31 (depends on 29) The apparatus according to claim 29 wherein said carrier fluid has a flash point greater than or equal to about 140° F. ### Claim 32 (depends on 30) The apparatus according to claim 30 wherein said carrier fluid has a flash point greater than or equal to about 140° F. ### Claim 33 (depends on 1) The apparatus according to claim 1 wherein said ink jet ink includes a carrier fluid, said carrier fluid being aqueous-based. ### Claim 34 (depends on 3) The apparatus according to claim 3 wherein said ink jet ink includes a carrier fluid, said carrier fluid being aqueous-based. ### Claim 35 (depends on 1) The apparatus according to claim 1 wherein said ink jet ink comprises a colloidal dispersion being characterized by at least one of a steric stabilization and an electrostatic stabilization. ### Claim 36 (depends on 3) The apparatus according to claim 3 wherein said ink jet ink comprises a colloidal dispersion being characterized by at least one of a steric stabilization and an electrostatic stabilization. ### Claim 37 (depends on 1) The apparatus according to claim 1 wherein said member is an intermediate member, said intermediate member comprising: a support; a compliant layer formed on said support; and wherein said support includes one of a drum, a web, and a planar linearly-movable member. ### Claim 38 (depends on 3) The apparatus according to claim 3 wherein said member is an intermediate member, said intermediate member comprising: a support; a compliant layer formed on said support; and wherein said support includes one of a drum, a web, and a planar linearly-movable member. ### Claim 39 (depends on 1) The apparatus according to claim 1 wherein said member is an intermediate member, said intermediate member comprising an electrode biasable by a source of potential including ground potential. ### Claim 40 (depends on 3) The apparatus according to claim 3 wherein said member is an intermediate member, said intermediate member comprising an electrode biasable by a source of potential including ground potential. ### Claim 41 (depends on 39) The apparatus according to claim 39 wherein said electrode has a hill-and-valley shape. ### Claim 42 (depends on 40) The apparatus according to claim 40 wherein said electrode has a hill-and-valley shape. ### Claim 43 (depends on 37) The apparatus according to claim 37 wherein said compliant layer has a thickness in a range of approximately between 0.5 mm and 10 mm. ### Claim 44 (depends on 38) The apparatus according to claim 38 wherein said compliant layer has a thickness in a range of approximately between 0.5 mm and 10 mm. ### Claim 45 (depends on 43) The apparatus according to claim 43 wherein said compliant layer has a thickness in a range of approximately between 0.5 mm and 3 mm. ### Claim 46 (depends on 44) The apparatus according to claim 44 wherein said compliant layer has a thickness in a range of approximately between 0.5 mm and 3 mm. ### Claim 47 (depends on 37) The apparatus according to claim 37 wherein said compliant layer has a resistivity less than about 1010 ohm-cm. ### Claim 48 (depends on 38) The apparatus according to claim 38 wherein said compliant layer has a resistivity less than about 1010 ohm-cm. ### Claim 49 (depends on 47) The apparatus according to claim 47 wherein said compliant layer has a resistivity less than about 107 ohm-cm. ### Claim 50 (depends on 48) The apparatus according to claim 48 wherein said compliant layer has a resistivity less than about 107 ohm-cm. ### Claim 51 (depends on 37) The apparatus according to claim 37 wherein said intermediate member has an optional thin outer layer which is formed on said compliant layer. ### Claim 52 (depends on 38) The apparatus according to claim 38 wherein said intermediate member has an optional thin outer layer which is formed on said compliant layer. ### Claim 53 (depends on 51) The apparatus according to claim 51 wherein said optional thin outer layer having a thickness in a range of approximately between 1 micrometer and 20 micrometers. ### Claim 54 (depends on 52) The apparatus according to claim 52 wherein said optional thin outer layer having a thickness in a range of approximately between 1 micrometer and 20 micrometers. ### Claim 55 (depends on 51) The apparatus according to claim 51 wherein said optional thin outer layer is made from a group of materials including sol-gels, ceramers, and polyurethanes. ### Claim 56 (depends on 52) The apparatus according to claim 52 wherein said optional thin outer layer is made from a group of materials including sol-gels, ceramers, and polyurethanes. ### Claim 57 (depends on 1) The apparatus according to claim 1 wherein said ink jet ink and said operational surface form a mutual interface for which interface a value of spreading coefficient does not exceed substantially zero. ### Claim 58 (depends on 3) The apparatus according to claim 3 wherein said ink jet ink and said operational surface form a mutual interface for which interface a value of spreading coefficient does not exceed substantially zero. ### Claim 59 (depends on 1) The apparatus according to claim 1 wherein said transfer mechanism includes at least one of an electrostatic transfer mechanism, a thermal transfer mechanism, and a pressure transfer mechanism. ### Claim 60 (depends on 59) The apparatus according to claim 59 wherein a charging device is used for applying an electrostatic charge to an ink-jet-ink-derived material included in a liquid-depleted image formed in an excess liquid removal process zone, said applying preceding a transfer of said liquid-depleted image to a receiver in said transfer process zone. ### Claim 61 (depends on 59) The apparatus according to claim 59 wherein a charging device is used for applying an electrostatic charge to an ink-jet-ink-derived material included in a liquid-depleted image formed in the image concentration/liquid removal process zone, said applying preceding a transfer of said liquid-depleted image to a receiver in said transfer process zone. ### Claim 62 (depends on 2) The apparatus according to claim 2 further including a mechanism for regenerating an operational surface of a member, which mechanism for regenerating is for use in the regeneration process zone, which mechanism for regenerating an operational surface substantially removes, from said operational surface, residual material not transferred in the transfer process zone, said mechanism comprising at least one of a group of devices, said group of devices including a cleaning blade, a squeegee, a scraper for scraping said operational surface, a cleaning roller to which said residual material adheres, a cleaning brush, a solvent applicator, and a wiper. ### Claim 63 (depends on 8) The apparatus according to claim 8 further including a mechanism for regenerating an operational surface of a member, which mechanism for regenerating is for use in the regeneration process zone, which mechanism for regenerating an operational surface substantially removes, from said operational surface, residual material not transferred in the transfer process zone, said mechanism comprising at least one of a group of devices, said group of devices including a cleaning blade, a squeegee, a scraper for scraping said operational surface, a cleaning roller to which said residual material adheres, a cleaning brush, a solvent applicator, and a wiper. ### Claim 64 A method of making an ink-jet-ink-derived image comprising the steps of: using an ink jet device to form on an intermediate member an ink image formed from an ink made from particles dispersed in a liquid; causing said particles dispersed in a liquid included in said ink image to become concentrated adjacent an operational surface of said intermediate member; removing a portion of said liquid from said ink image so as to form a liquid-depleted ink-jet-ink-derived material image; and transferring said liquid-depleted ink-jet-ink-derived material image from said operational surface to another member.