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US 6,689,732 B1Granted
Detergent compositions having a specific hydrophobic peroxyacid bleaching system and anionic surfactant
AssigneeThe Procter & Gamble Company
InventorsNour-Eddine Guedira, Dawn Constance Ward
Life of this patent
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Abstract
Granular detergent compositions, particularly phosphate-containing detergent compositions, contain a specific hydrophobic peroxyacid bleaching system and a specific anionic surfactant system. The compositions are suitable for use in laundry washing methods.
Claims13
A detergent composition comprising
- (a) from 1% to 70%, by weight of a hydrophilic anionic surfactant system, comprising:
- (i) at least 50% by weight of the system one or more alkyl mono-sulphate and/or mono-sulphonate surfactants;
- and
- (I) a dianionic surfactants of the formula
- where R is an, optionally substituted, allyl, alkyl, alkenyl, aryl, akaryl, ether, ester, amine or amide group of chain length C1 to C28, or hydrogen;
- A and B are independently selected from alkylene, alkenylene, (poly)alkoxylene, hydroxyalkylene, arylalkylene or amido alkylene groups of chain length C1 to C28;
- whereby A, B, and R in total contain from 4 to about 31 carbon atoms;
- X and Y are anionic groups from the group comprising, carboxylate, sulfate and sulfonate, wherein at least one of X or Y is a sulfate group;
- z is 0 or 1;
- and M is a cationic counterion, said anionic surfactant system further optionally containing a member selected from the group consisting of;
- (ii) one or more additional anionic surfactants selected from the group consisting of:
- (II) an alkyl ester sulphonate surfactant of the formula
- R1—CH(SO3M)—(A)x—C(O)—OR2
- wherein R1 is a C6-C22 hydrocarbyl, R2 is a C1-C6 alkyl, A is a C6-C22 alkylene, alkenylene, x is 0 or 1, and M is a cation;
- and
- (III) an alkyl alkoxylated sulphate of the formula
- R5O(A)mSO4M
- wherein R5 is a C6-C24 alkyl or hydroxyalkyl group, A is an alkoxy unit, the average of m is at least 5, and M is a cationic counterion;
- and
- b) from 0.01% to 10.0%, by weight of the composition of a hydrophobic bleaching system comprising
- (i) a peroxylic acid of the formula
- R1—CO3M
- wherein R1 has at least 6 carbon atoms, and M is a counterion;
- or
- (ii) a percarboxylic acid precursor of the formula
- R1—CO—L
- wherein L is a leaving group which is linked to the R1—CO— group with an oxygen atom, and R1 has at least 6 carbon atoms;
- or mixtures of (i) and (ii);
- wherein said percarboxylic acid or said percarboxylic acid precursor is derived from a parent carboxylic acid having a critical micelle concentration of less than 0.5 moles/liter wherein said critical micelle concentration is measured in aqueous solution at a temperature of 20° C.-50° C. and with the proviso that dianionic surfactant of formula (I) wherein R has 18 or 20 C-atoms, is present at a level of 2% or 2.7% by weight of the composition, the weight ratio of said dianionic surfactant to the hydrophobic bleaching agent is not 1:1 or 1.35:1.
26 more elements
Dependencies are inferred from the claim text.