Alicyclic hydrocarbon copolymer
AssigneeZeon Corporation
InventorTsutomu Nagamune
Life of this patent
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Abstract
A novel alicyclic hydrocarbon copolymer having a weight average molecular weight (Mw) of 1,000-1,000,000 a comprising repeating units (a) having an alicyclic structure and repeating units (b) having a chainlike structure; the sum of repeating units (a) and repeating units (b) being at least 90 wt. % based on the copolymer, and the content of repeating units (b) being at least 1 wt. % but smaller than 10 wt. %, based on the copolymer; and the chain of repeating units (a) satisfying the formula: A≦0.3×B where A=weight average molecular weight of the chain of repeating units (a), and B=Mw of the copolymer×(number of repeating units (a)/number of the total repeating units constituting the copolymer). The copolymer exhibits low birefringence and high mechanical strength. A process for producing the copolymer is provided.
Claims16
An alicyclic hydrocarbon copolymer having a weight average molecular weight in the range of 1,000 to 1,000,000 and comprising repeating units (a) represented by the following general formula (1), and at least one kind of repeating units (b) selected from those which are represented by the following general formula (2) and/or the following general formula (3);
- the sum of repeating units (a) and repeating units (b) being at least 90% by weight based on the weight of the copolymer, and the content of repeating units (b) being at least 1% by weight but smaller than 10% by weight, based on the weight of the copolymer;
- and the chain of repeating units (a) satisfying the following formula:
- A≦0.3×B
- where A=weight average molecular weight of the chain of repeating units (a), and
- B=weight average molecular weight (Mw) of the alicyclic hydrocarbon copolymer×(number of repeating units (a)/number of the total repeating units constituting the alicyclic hydrocarbon copolymer),
- wherein X in formula (1) is an alicyclic hydrocarbon group, R1 through R13 in formulae (1), (2) and (3) independently represent a hydrogen atom, a chainlike hydrocarbon group, a halogen atom, an alkoxy group, a hydroxy group, an ether group, an ester group, a cyano group, an amide group, an imide group, a silyl group, and a chainlike hydrocarbon group having one or more polar groups as a substituent which are selected from a halogen atom, an alkoxy group, a hydroxy group, an ether group, an ester group, a cyano group, an amide group, an imide group and a silyl group;
- and in formula (3) represents a carbon-carbon saturated or unsaturated bond.
A process for producing an alicyclic hydrocarbon copolymer comprising:
- a step of copolymerizing an aromatic vinyl compound and/or an alicyclic vinyl compound with other copolymerizable monomer to obtain a hydrocarbon copolymer satisfying the following formula:
- D≦0.3×E
- where D=weight average molecular weight of the chain of repeating units derived from the aromatic vinyl compound and/or the alicyclic vinyl compound, and
- E=weight average molecular weight (Mw) of the alicyclic hydrocarbon copolymer×(number of repeating units derived from the aromatic vinyl compound and/or the alicyclic vinyl compound/number of the total repeating units constituting the alicyclic hydrocarbon copolymer);
- and
- a step of hydrogenating carbon-carbon unsaturated bonds in the unsaturated rings and the backbone chain of the alicyclic hydrocarbon copolymer.
A process for producing an alicyclic hydrocarbon copolymer comprising:
- a step of copolymerizing an aromatic vinyl compound and/or an alicyclic vinyl compound with other copolymerizable monomer while the aromatic vinyl compound and/or the alicyclic vinyl compound, and the copolymerizable monomer are sequentially added to a polymerization system, and
- a step of hydrogenating carbon-carbon unsaturated bonds in the unsaturated rings and the backbone chain of the alicyclic hydrocarbon copolymer
- wherein the alicyclic hydrocarbon copolymer comprises repeating units (a) represented by the following general formula (1), and at least one kind of repeating units (b) selected from those which are represented by the following general formula (2) and/or the following general formula (3);
- the sum of repeating units (a) and repeating units (b) being at least 90% by weight based on the weight of the copolymer, and the content of repeating unit (b) being at least 1% by weight but smaller than 10% by weight, based on the weight of the copolymer;
- wherein X in formula (1) is an alicyclic hydrocarbon group R1 through R13 in formulae (1), (2) and (3) independently represent a hydrogen atom, a chainlike hydrocarbon group, a halogen atom, an alkoxy group, a hydroxy group, an ether group, an ester group, a cyano group, an amide group, an imide group, a silyl group, and a chainlike hydrocarbon group having one or more polar groups as a substituent which are selected from a halogen atom, an alkoxy group, a hydroxy group, an ether group, an ester group, a cyano group, an amide group, an imide group and a silyl group;
- and in formula (3) represents a carbon-carbon saturated or unsaturated bond.
Dependencies are inferred from the claim text.