Flame-resistant polycarbonate ABS moulding compounds
AssigneeBayer Aktiengesellschaft
InventorsThomas Eckel, Michael Zobel, Dieter Wittmann, Nikolaus Janke
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Abstract
Flame-retardant thermoplastic moulding compositions containing an aromatic polycarbonate or polyestercarbonate, a graft polymer, a thermoplastic vinyl copolymer, a fluorinated polyolefin, 0.5 to 20 parts by weight of at least one phosphorus compound of general formula (I) wherein the average degree of polycondensation N of component D is always >5, a very finely divided inorganic powder with an average diameter of 0.1 to 200 nm and/or a monophosphorus compound, wherein the sum of the parts by weight of all the components is 100.
Claims17
A flame-retardant thermoplastic moulding composition containing
- A 5 to 95 parts by weight of an aromatic polycarbonate or polyestercarbonate
- B. 0.5 to 60 parts by weight of at least one graft polymer of
- B.1 5 to 95 wt. % of one or more vinyl monomers on
- B.2 95 to 5 wt. % of one or more graft substrates with a glass transition temperature <10° C.
- C. 0 to 45 parts by weight of a thermoplastic vinyl copolymer,
- D. 0.5 to 20 parts by weight of at least one phosphorus compound of general formula (I)
- wherein
- R1, R2, R3, and R4, independently of each other, each represent C1- to C8-alkyl, C5- to C6-cycloalkyl, C6- to C20-aryl or C7- to C12-aralkyl, which are optionally halogenated,
- n represents 0 or 1, which are independent of each other,
- N is an average number from 5 to 30,
- X represents a mono- or polynuclear aromatic radical containing 6 to 30 carbon atoms,
- E 0 to 5 parts by weight of a fluorinated polyolefin, and
- F.1 0.5 to 40 parts by weight of a finely divided inorganic powder with an average particle diameter of less than or equal to 200 nm, and/or
- F.2 05 to 20 parts by weight of a monophosphorus compound of formula (IA)
- wherein
- R11, R12 and R13, independently of each other, denote C1-C8-alkyl, which is optionally halogenated, or C6-C20-aryl, which is optionally halogenated,
- m1 denotes 0 or 1, and
- n1 denotes 0 or 1,
- wherein the sum of all the parts by weight of all the components is 100.
Dependencies are inferred from the claim text.