Precipitated aragonite and a process for producing it
Assignee3P Technologies Ltd.
InventorIsaac Yaniv
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Abstract
Disclosed is a novel form of particulate precipitated aragonite calcium carbonate and a novel process for producing it.
Claims51
A precipitated aragonite calcium carbonate (PACC) having a specific gravity less than 2.5 g/cm3, when determined by a method that comprises:
- a. drying said PACC for 12 hours at 120° C.;
- b. mixing a weighed quantity (Wc) of the dried PACC with a weighed quantity (Wo) of tall oil having a density 0.93 g/cm3;
- c. sonicating the mixture in an ultrasound bath for 20 minutes;
- d. measuring the total volume of the mixture (V) and the total weight of the mixture (W) at 20-22° C. and calculating the density D therefrom from the following equation
- D=W/V;
- and
- e. calculating the specific gravity (S.G.) of the PACC from the following equation:
- 1/D=[Wc(Wo+Wc)]/S.G.+[Wo(Wo+Wc)]/0.93.
A process for producing a precipitated aragonite calcium carbonate (PACC), which comprises reacting a reaction mixture of an aqueous calcium hydroxide slurry, including at least one active agent selected from the group consisting of carboxylic acids of formula CH3(CH2)nCOOH, where n is 7, 8 or 9, carboxylate salts thereof, esters thereof, anhydrides thereof, acyl halides thereof and ketenes thereof of the formula CH3(CH2)n−1C═C═O, wherein n is as defined previously, with carbon dioxide or a gas containing carbon dioxide, wherein at least one of the active agent added to the reaction mixture or reaction conditions of temperature, pH, mode of operation and reactant concentrations, are selected to yield precipitated aragonite calcium carbonate with a specific gravity of less than 2.5 g/cm3, when determined by a method that comprises:
- a. drying said PACC for 12 hours at 120° C.;
- b. mixing a weighed quantity (Wc) of the dried PACC with a weighed quantity (Wo) of tall oil having a density 0.93 g/cm3;
- c. sonicating the mixture in an ultrasound bath for 20 minutes;
- d. measuring the total volume of the mixture (V) and the total weight of the mixture (W) at 20-22° C. and calculating the density D therefrom from the following equation
- D=W/V;
- and
- e. calculating the specific gravity (S.G.) of the PACC from the following equation:
- 1/D=[Wc(Wo+Wc)]/S.G.+[Wo(Wo+Wc)]/0.93.
A process for producing a precipitated aragonite calcium carbonate (PACC), which comprises reacting in a reaction mixture an aqueous calcium hydroxide slurry with carbon dioxide or a gas containing carbon dioxide, wherein at least one active agent is included in the reaction mixture, each such active agent being selected from the group consisting of carboxylic acids of the formula CH3(CH)nCOOH, wherein n is 7, 8 or 9, and carboxylate salts, acid anhydrides, esters, and acyl halides of said carboxylic acids, and ketenes of the formula CH3(CH2)n−1C═C═O, wherein n is as defined previously.
Dependencies are inferred from the claim text.