A solvent-free, radiation-curable composition comprising a polymer binder, which is a reactive pre-formed thermoplastic or elastomeric polymer/oligomer having reactive functional groups, a monofunctional and/or bifunctional acrylic monomer, a multifunctional (more than 2 reactive groups) acrylated/methacrylated monomer, and a photoinitiator, where all the constituents are mutually miscible forming a homogeneous viscous blend without the addition of an organic solvent and wherein the composition including the reactive functional groups of the polymer/oligomer is polymerized to form a cured matrix.