Catalytic support with an oxide base from a metal belonging to the SVI group of the periodic table, its preparation and its uses
AssigneeTotal Raffinage Distribution S.A.
InventorsPedro Da Silva, Marc Bisson, Alain Milan, Sebastien Decker, Joeri Denayer
Life of this patent
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Abstract
A catalytic support includes a substantial quantity of at least one SVI group Periodic Table metal oxide in which is incorporated silica. The mass ratio between the quantity of SVI group metal oxide and the quantity of silica it contains ranges between 5 and 70, the SVI group metal oxide is in crystalline form, and the specific surface of the support is greater than or equal to 160 m2/g.
Claims37
Catalytic support comprising a quantity of at least one metal oxide selected from the group consisting of zirconia, titanium oxide, and a mixture thereof, in which is incorporated silica, wherein the mass ratio between the quantity of the metal oxide and the quantity of silica it contains ranges between 5 and 70, the metal oxide is in crystalline form, and the specific surface of the support is greater than or equal to 160 m2/g, wherein the support has a pore volume greater than or equal to 0.25 cm3/g and less than or equal to 0.60 cm3/g.
Procedure for the preparation of a catalyst support, comprising the following steps:
- (a) from a solution of at least one salt of at least one of zirconium and titanium, precipitating the corresponding metal oxide(s);
- (b) ripening under reflux the precipitate obtained;
- (c) adding silica;
- (d) ripening the mixture, under agitation;
- (e) washing, filtering and then drying the solid obtained from step (d);
- (f) shaping the solid;
- and
- (g) calcining the solid to thereby obtain a catalytic support comprising a quantity of at least one metal oxide selected from the group consisting of zirconia, titanium oxide, and a mixture thereof, in which is incorporated silica, wherein the mass ratio between the quantity of the metal oxide and the quantity of silica it contains ranges between 5 and 70 the metal oxide is in crystalline form, and the specific surface of the support is greater than or equal to 160 m2/q, wherein the support has a pore volume greater than or equal to 0.25 cm3/q and less than or equal to 0.60 cm3/g.
Dependencies are inferred from the claim text.