Crosslinkable creping adhesive formulations applied to a dryer surface or to a cellulosic fiber
AssigneeFort James Corporation
InventorsPhuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
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AssigneeFort James Corporation
InventorsPhuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
Estimating the term…
Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means. In the method for producing the absorbent creped cellulosic sheets, the zirconium crosslinking agent is advantageously applied directly and separately on the Yankee dryer at the time the base polymer is applied to the surface. The crosslinking agent functions to crosslink the polymer to the fibrous web. The absorbent paper products are used as bathroom tissue and towels.
A method of using a creping adhesive comprising applying said adhesive either to a dryer surface or to a cellulosic fiber, wherein the adhesive comprising a polyvinyl alcohol-vinyl amine copolymer and a crosslinking agent for crosslinking said polyvinyl alcohol-vinyl amine copolymer to a fibrous web, said crosslinking agent selected from the group consisting of zirconium compounds wherein the zirconium has a valence of plus four, and wherein the adhesive is applied in the range of about 0.1 to 0.8 pounds of the adhesive for each ton of cellulose fiber in the presence of a softener or debonder applied in the range of about one (1) to ten (10) pounds per ton of cellulosic fiber wherein the fiber and adhesive together exhibit a peel force of about 300 to 500 grams per 12 inches when measured on a paper machine having a speed of less than one hundred fifty feet per minute.
Dependencies are inferred from the claim text.