Semiconductor impurity concentration testing apparatus and semiconductor impurity concentration testing method

A semiconductor impurity concentration testing apparatus, comprising:

• a terahertz pulse light source that irradiates terahertz pulse light on a semiconductor material;
• a light detector that detects transmitted pulse light having been transmitted through the semiconductor material;
• a terahertz time domain measurement device that obtains a spectral transmittance based upon an amplitude and a phase of the transmitted pulse light calculated by performing a Fourier transform on a time-series waveform of an electric field intensity of the transmitted pulse light detected by said light detector;
• and
• an arithmetic operation unit that calculates an impurity concentration in the semiconductor material based upon said spectral transmittance, wherein:
• said terahertz time domain measurement device operates (1) a first step in which a time-series waveform of the electric field intensity of the transmitted pulse light obtained by inserting the semiconductor material in an optical path and a time-series waveform of the electric field intensity obtained without inserting the semiconductor material in the optical path are respectively obtained, and an amplitude and a phase of the transmitted pulse light are calculated by performing a Fourier transform on each of the time-series waveforms and (2) a second step in which a measurement value of a complex amplitude transmittance as the spectral transmittance is calculated based upon a ratio of the Fourier components of the time-series waveform obtained by inserting and without inserting the semiconductor material in the optical path;
• said arithmetic operation unit operates (1) a third step in which a complex refractive index of the semiconductor material is calculated based upon a theoretical value of a complex amplitude transmittance which is equivalent to a value obtained by inserting the semiconductor material in the optical path and the measurement value of the complex amplitude transmittance and (2) a fourth step in which a light absorption coefficient of the semiconductor material is calculated with the complex refractive index based upon Lambert's light absorption theory;
• the light absorption coefficient of the semiconductor material with known impurity concentration is calculated by performing the first step through the fourth step;
• the light absorption coefficient of the semiconductor material to be tested is calculated by performing the first step through the fourth step;
• and
• said arithmetic operation unit calculates a conversion coefficient between the impurity concentration and the calculated light absorption coefficient of the semiconductor material with known impurity concentration and calculates the impurity concentration in the semiconductor material to be tested based upon the calculated light absorption coefficient of the semiconductor material to be tested and the conversion coefficient.

A semiconductor impurity concentration testing method comprising:

• expanding a light flux of terahertz pulse light and irradiating in a batch the expanded light flux over an entire surface of a semiconductor material;
• detecting in a batch transmitted pulse light having been transmitted through the semiconductor material irradiated with the expanded light flux;
• calculating a spectral transmittance based upon a time-series waveform of an electric field intensity of the transmitted pulse light;
• calculating an impurity concentration in the semiconductor material based upon the spectral transmittance;
• a first step in which time-series waveforms of the electric field intensity of the transmitted pulse light obtained by inserting and without inserting a semiconductor material with known impurity concentration in an optical path are respectively obtained, and an amplitude and a phase of the transmitted pulse light are calculated by performing a Fourier transform on each of the time-series waveforms;
• a second step in which a measurement value of a complex amplitude transmittance as the spectral transmittance is calculated based upon a ratio of the Fourier components of the time-series waveforms obtained by inserting and without inserting the semiconductor material with known impurity concentration in the optical path;
• a third step in which a complex refractive index of the semiconductor material with known impurity concentration is calculated based upon a theoretical value of a complex amplitude transmittance which is equivalent to a value obtained by inserting the semiconductor material in the optical path and the measurement value of the complex amplitude transmittance;
• a fourth step in which a light absorption coefficient of the semiconductor material with known impurity concentration is calculated with the complex refractive index based upon Lambert's light absorption theory;
• and
• a fifth step in which a conversion coefficient between the impurity concentration and the light absorption coefficient of the semiconductor material with known impurity concentration calculated in the fourth step is calculated, wherein:
• in said step of calculating a spectral transmittance, (1) time-series waveforms of the electric field intensity of the transmitted pulse light obtained by inserting and without inserting a semiconductor material to be tested in an optical path are respectively obtained, and an amplitude and a phase of the transmitted pulse light are calculated by performing a Fourier transform on each of the time-series waveforms and (2) a measurement value of a complex amplitude transmittance as the spectral transmittance is calculated based upon a ratio of the Fourier components of the time-series waveforms obtained by inserting and without inserting the semiconductor material to be tested in the optical path;
• and
• in said step of calculating an impurity concentration, (1) a complex refractive index of the semiconductor material to be tested is calculated based upon a theoretical value of a complex amplitude transmittance which is equivalent to a value obtained by inserting the semiconductor material in the optical path and the measurement value of the complex amplitude transmittance, (2) a light absorption coefficient of the semiconductor material to be tested is calculated with the complex refractive index based upon Lambert's light absorption theory and (3) the impurity concentration in the semiconductor material to be tested is calculated based upon the light absorption coefficient of the semiconductor material to be tested and the conversion coefficient calculated in the fifth step.

A semiconductor impurity concentration testing method comprising:

• expanding a light flux of terahertz pulse light and irradiating in a batch the expanded light flux over an entire surface of a semiconductor material;
• detecting in a batch transmitted pulse light having been transmitted through the semiconductor material irradiated with the expanded light flux;
• calculating a spectral transmittance based upon a time-series waveform of an electric field intensity of the transmitted pulse light;
• and
• calculating an impurity concentration in the semiconductor material based upon the spectral transmittance, wherein;
• an analysis is executed based upon Lambert's light absorption theory to calculate an oxygen concentration a nitrogen concentration and a carbon concentration in the semiconductor material;
• and
• terahertz pulse light within a frequency range of 20 THz-80 THz is irradiated onto a semiconductor material when an oxygen concentration and a nitrogen concentration in the semiconductor material is calculated.