Noble metal containing hydrogenation catalyst for selective hydrogenation of 1, 4 butynediol to 1, 4 butenediol, and a process for the preparation thereof
AssigneeCouncil of Scientific and Industrial Research
InventorsRaghunath Vitthal Chaudhari, Chandrashekhar Vasant Rode, Rengaswamy Jaganathan, Manisha Madhukar Telkar, Vilas Hari Rane
Life of this patent
Estimating the term…
Abstract
A hydrogenation catalyst of the general formula AB(y)C(z) wherein A is a support comprising of a salt of a Group II A metal or zeolite, B is a noble metal selected from Pt or Pd, y=0.2 to 10%, C is nickel and z=0 to 15.0%, with the proviso that when B is Pt, z=0.
Claims7
A process for the preparation of a hydrogenation catalyst of the general formula AB(y)C(z) wherein A is a support comprising of a salt of a Group II A metal or zeolite, B is a noble metal selected from Pd or Pt, y=0.2 to 10%, C is nickel and z=0 to 15.0%, with the proviso that when B is Pt, z=0, said process comprising:
- i. dissolving a noble metal precursor in a mineral acid by stirring at a temperature in the range between 60° C. to 120° C.;
- ii. diluting the above solution by adding water;
- iii. adjusting the pH of the solution to the range of 8-12 by adding a base;
- iv. adding a support to the above solution;
- v. heating the mixture to a temperature in the range of 60° C. to 120° C.;
- vi. reducing the above mixture using a conventional reducing agent;
- vii. separating the catalyst formed by any conventional method;
- viii. washing and drying the product to obtain the catalyst.
Dependencies are inferred from the claim text.