Process for producing bisphenol A
AssigneeIdemitsu Petrochemical Co., Ltd.
InventorMasahiro Iwahara
Life of this patent
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Abstract
Provided is a process for producing bisphenol A having a stable color tone at a high temperature and free from coloration, which comprises reacting phenol with acetone in the presence of an acid ion-exchange resin as a catalyst and an alkyl mercaptan as a cocatalyst, wherein a concentration of an organosulfur compound in a crystallization starting material obtained by conducting the reaction under conditions that a reaction temperature is between 60 and 100° C., a phenol to acetone molar ratio is between 6 and 13 and an acetone to alkyl mercaptan molar ratio is between 13 and 25, distilling off unreacted acetone, by-product water and the alkyl mercaptan as the cocatalyst and further distilling off excess phenol is measured, and maintained at 200 weight ppm or less.
Claims20
A process for producing bisphenol A, which comprises:
- reacting phenol with acetone in the presence of an acid ion-exchange resin as a catalyst and a cocatalyst consisting essentially of an alkyl mercaptan, wherein a concentration of an organosulfur compound in a crystallization starting material obtained by conducting the reaction under conditions that a reaction temperature is between 60 and 100° C., a phenol to acetone molar ratio is between 6 and 13 and an acetone to alkyl mercaptan molar ratio is between 13 and 25, distilling off unreacted acetone, by-product water and the alkyl mercaptan as the cocatalyst and further distilling off excess phenol is maintained at 200 weight ppm or less;
- separating the crystallization starting material into phenol adduct crystals and a crystallization mother liquor;
- and
- recycling the crystallization mother liquor, wherein a part or the whole of the crystallization mother liquor is isomerized and recycled into the crystallization starting material.
Dependencies are inferred from the claim text.