Film-type adhesive for electronic components, and electronic components bonded therewith
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsTsuyoshi Honda, Nobuhiro Ichiroku, Toshio Shiobara
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Abstract
A film-type adhesive for electronic components comprises a polyimide resin made up of specific repeating units and having a weight-average molecular weight of 5,000-150,000 in combination with an epoxy resin bearing at least two glycidyl groups per molecule. The adhesive has a weight ratio of the polyimide resin to the epoxy resin within a range of 50/50 to 5/95, and a film thickness of 20-150 μm. Such a film-type adhesive makes it possible to simplify and shorten the duration of assembly operations for electronic components having various types of adherend surfaces.
Claims9
A film-type adhesive for electronic components, consisting essentially of (A) a polyimide resin comprising repeating units of the following structural formula (1) and having a weight-average molecular weight of 5,000 to 150,000 and (B) an epoxy resin having the following structural formula (2), (3) or (4);
- which adhesive has a weight ratio of component (A) to component (B) of 45/55 to 5/95 and a film thickness of 20 to 150 μm,
- wherein X is at least one tetravalent organic group selected from the group consisting of:
- Y is a divalent organic group composed of 30 to 99 mol % of at least one phenolic hydroxyl group-bearing aromatic diamine residue Y1 selected from among
- and 70 to 1 mol % of at least one aromatic diamine residue Y2 selected from among
- Z is a siloxane diamine residue of the following formula:
- wherein R1 is a substituted or unsubstituted monovalent hydrocarbon group of 1 to 10 carbon atoms, the letter “a” is an integer from 1 to 6, and b is an integer from 1 to 120, and
- the letters m and n are positive numbers which satisfy the conditions 0.70≦m/(m+n)≦0.98 and 0.02≦n/(m+n)≦0.30,
- and formulas (2), (3) and (4) are as follows:
- wherein G is a group of the formula:
- Q is a group selected from the group consisting of:
- the letter n is an integer from 0 to 5, and
- R2 is hydrogen or a monovalent hydrocarbon group of 1 to 5 carbon atoms.
Dependencies are inferred from the claim text.