An optical diffraction element for use as a diffraction grating or a hologram installed in an optical coupler, a polariscope, a wave divider, a wavelength filter, a reflector or a mode transducer, said optical diffraction element comprising:
- a glass substrate;
- a thin film formed with a thickness on a surface of said glass substrate, said thin film being substantially of an inorganic material showing a superior energy absorption characteristic relative to that of said glass substrate;
- and
- a convexo-concave structure formed from said thin film by radiation of a laser beam having a periodic optical intensity distribution, said structure having concave portions with a depth;
- wherein the depth of said concave portions of said convexo-concave structure is equal to the thickness of said thin film.