Polymerization of ethylene oxide using metal cyanide catalysts
AssigneeDow Global Technologies LLC
InventorsKatherine S. Clement, Louis L. Walker, Richard M. Wehmeyer, Robert H. Whitmarsh, David C. Molzahn, William P. Dianis, David E. Laycock, John W. Weston, Richard J. Elwell
Life of this patent
Estimating the term…
Abstract
Ethoxylations of various initiator compounds are performed in the presence of metal cyanide catalysts. The catalysts surprisingly form a wide variety of polyether products that in most cases contain only small amounts of high molecular weight poly(ethylene oxide).
Claims9
A process for preparing a block polyether, comprising forming a mixture of an initiator compound having one or more oxyalkylatable groups, an initial charge of ethylene oxide and a metal cyanide catalyst complex, and subjecting the mixture to conditions sufficient to ethoxylate the oxyalkalatable groups of the initiator, and feeding another alkylene oxide or mixture of another alkylene oxide and a copolymerizable monomer to the reactor under polymerization conditions once the catalyst has been activated and the initial charge of ethylene oxide has begun to polymerize.
A block copolymer containing internal blocks of polymerized ethylene oxide and external blocks of another polymerized alkylene oxide, wherein said internal and external blocks are prepared using a DMC catalyst.
Dependencies are inferred from the claim text.