Process to produce a homogeneous polyethylene material
AssigneeBorealis Technology Oy
InventorsOle Jan Myhre, Bjarne Jansen, Auli Nummila-Pakarinen, Jari Äärilä
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AssigneeBorealis Technology Oy
InventorsOle Jan Myhre, Bjarne Jansen, Auli Nummila-Pakarinen, Jari Äärilä
Estimating the term…
The present invention concerns a process for producing homogeneous polyethylene compositions and processes for making high density, medium density and low density films therefrom. The process comprises carrying out the polymerization in the presence of an ethylene-polymerizing catalyst system in a multistage reaction sequence of successive polymerization stages, at least one of which is a loop polymerization stage, and at least one of which is a gas phase polymerization stage. According to the invention, said loop polymerization stage is operated using a diluent selected from the group of linear and branched C4-C6 hydrocarbons and/or mixtures thereof. The reactor sequence is operated with different amounts of hydrogen and comonomers to produce a high molecular weight portion in one of the polymerization stages and a low molecular weight portion in another, so as to provide bimodal polyethylene composition with a low molecular weight part having an MFR2 of 250 g/10 min or more. The obtained material is homogenous and the fines level in the process is low.
A process for producing a polyethylene composition in the presence of an ethylene-polymerizing catalyst system in a multistage reaction sequence of successive polymerization stages, at least one of which is a loop polymerization stage and at least one of which is a gas phase polymerization stage, wherein the level of fines produced in said loop polymerization stage is less than 15 wt %, and said loop polymerization stage being operated with an inert diluent selected from the group of linear and branched C4-C6 hydrocarbons and/or mixtures thereof, said reactor sequence being operated with different amounts of hydrogen and comonomers to produce a high molecular weight portion in one of the polymerization stages and a low molecular weight portion in another so as to provide a bimodal high density polyethylene with a low molecular weight part having a MFR2 of 250 g/10 min or more.
A process for producing high density polyethylene films, comprising
A process for preparing medium density polyethylene films, comprising
A process for preparing low density polyethylene films, comprising
The process according to any one of claims 1922, wherein the film exhibits a number of gels lower than 50 in an area of A4 size.
A process for producing high density polyethylene films, comprising
A process for producing medium density polyethylene films, comprising
A process for producing low density polyethylene films, comprising
A method for reducing the level of fine polymer in a process in which ethylene is polymerized in the presence of an ethylene-polymerizing catalyst system in a multistage reaction sequence of successive polymerization stages, at least one of which is a loop polymerization stage and at least one of which is a gas phase polymerization stage, wherein the level of fines produced in said loop polymerization stage is less than 15 wt %, and said loop polymerization stage being operated with an inert diluent, said reactor sequence being operated with different amounts of hydrogen and comonomers to produce a high molecular weight portion in one of the polymerization stages and a low molecular weight portion in another so as to provide a bimodal polyethylene composition having a MFR21 of 3-50 g/10 min, the low molecular weight part having a MFR2 of 250 g/10 min or more, wherein the diluent is selected from the group of linear and branched C4-C6 hydrocarbons and/or mixtures thereof.
Dependencies are inferred from the claim text.