Polyolefin-based composite resin composition having high strength and low linear expansion
AssigneeHyundai Motor Company
InventorsBong-Hyun Park, Sung-Jun Lee
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Abstract
The present invention relates to a polyolefin-based composite resin composition having excellent dimensional stability due to low mold shrinkage, low linear thermal expansion coefficient and low heat sag as well as having excellent mechanical strength, impact resistance, heat resistance, injection molding plasticity and surface smoothness of a product. The composition includes: 30-80% by weight of a crystalline ethylene-propylene copolymer; 5-40% by weight of an ethylene-α-olefin copolymer; 5-40% by weight of an inorganic fortifier; and additives.
Claims21
A polyolefin-based composite resin composition having high strength and low linear thermal expansion comprising:
- (i) 30-80% by weight of a crystalline ethylene-propylene copolymer;
- (ii) 5-40% by weight of an ethylene-α-olefin copolymer;
- (iii) 5-40% by weight of an inorganic fortifier;
- and
- (iv) additives;
- wherein said crystalline ethylene-propylene copolymer contains 0.5-35% by weight of ethylene-propylene rubber and comprises at least one ethylene-propylene copolymer having a melt index of 5-60 g/10 mm (230° C. 2.16 kg) wherein said ethylene-propylene copolymer consists of 1-50% by weight of ethylene and 50-99% by weight of propylene.
A polyolefin-based composite resin composition having high strength and low linear thermal expansion comprising:
- (i) 30-80% by weight of a crystalline ethylene-propylene copolymer:
- (ii) 5-40% by weight of an ethylene-□-olefin copolymer:
- (iii) 5-40% by weight of an inorganic fortifier;
- and
- (iv) additives, wherein said ethylene-α-olefin copolymer contains 20-50% by weight of propylene and 5-20 % by weight of ethylene-propylene copolymer rubber having a melt index of 0.1-5 g/10 mm (230° C., 2.16 kg).
A polyolefin-based composite resin composition having high strength and low linear thermal expansion comprising:
- (i) 30-80% by weight of a crystalline ethylene-propylene copolymer;
- (ii) 5-40% by weight of an ethylene-α-olefin copolymer;
- (iii) 5-40% by weight of an inorganic fortifier;
- and
- (iv) additives, wherein said ethylene-α-olefin copolymer contains 20-50% by weight of octene and 5-20% by weight of ethylene-octene copolymer rubber having a melt index of 0.1-15 g/10 mm (230° C., 2.16 kg).
A polyolefin-based composite resin composition having high strength and low linear thermal expansion comprising:
- between about 45% and about 55% by weight of a crystalline ethylene-propylene copolymer, wherein at least 30% by weight of the composition comprises a crystalline ethylene-propylene copolymer with a melt index of between about 40 and about 60;
- between about 20 and about 30% by weight of an ethylene-α-olefin copolymer, wherein at least 5-20% by weight of the ethylene-α-olefin is an ethylene-propylene copolymer containing 20-50% by weight of propylene and 5-20% by weight of ethylene-propylene copolymer rubber having a melt index of about 0.5 to about 4 g/10 mm (230° C., 2.16 kg), or contains 20-50% by weight of octene and 5-20% by weight of ethylene-octene copolymer rubber having a melt index of about 3 to about 15 g10 mm (230° C., 2.16 kg), or a mixture thereof between about 20 and about 30% by weight of an inorganic fortifier with an aspect ratio of at least 6 and with an average particle size of between about 1 and about 8 microns;
- and
- between about 0.2 and about 3% of additives.
A polyolefin-based composite resin composition having high strength and low linear thermal expansion comprising:
- between about 40% and about 60% by weight of a crystalline ethylene-propylene copolymer manufactured by polymerization of monomers in the presence of a combinatory catalyst, a Ziegler-Natta type catalyst, and an alkylaluminium compound or under a catalyst containing a titanium compound or a magnesium compound and containing between about 18 and about 34% of ethylene-propylene rubber, wherein the degree of crystallinity is between about 20 and about 30% and the melt index of the crystalline ethylene-propylene copolymer of the present invention is preferred to be between about 5 and about 60 g/10 mm (210° C., 2.16 kg);
- between about 15 and about 35% by weight of an ethylene-α-olefin copolymer wherein the α-olefin is selected from the group consisting of 1-propylene, 1-butene, 1-hexene, 1-octene, or mixtures thereof, wherein the ethylene-α-olefin copolymer is polymerized from monomers using a Ziegler-Natta catalyst, a vanadium-based catalyst, a chromium-based catalyst, or mixtures thereof, and comprise between 20 and 50% by weight of the α-olefin, and at least 5% by weight of ethylene-α-olefin copolymer rubber;
- between about 15and about 30% by weight of an inorganic fortifier with an aspect ratio of at least 6 and with an average particle size of between about 1 and about 8 microns;
- and
- between about 0.2 and about 3% of additives.
Dependencies are inferred from the claim text.