Fabric maintenance compositions comprising certain cationically charged fabric maintenance polymers

A composition for providing enhanced fabric protection to fabric, said composition comprising:

• a) from 0.05% by weight, of a polymer, copolymer, or mixtures thereof, said polymer or copolymer comprising one or more units selected from the group consisting of:
• I) linear polymer units having the formula:
• wherein each R1 is independently
• a) hydrogen;
• b) C1-C4 alkyl;
• c) substituted or unsubstituted phenyl;
• d) substituted or unsubstituted benzyl;
• e) carbocyclic;
• f) heterocyclic;
• g) and mixtures thereof;
• each R2 is independently
• a) hydrogen;
• b) halogen
• c) C1-C4 alkyl;
• d) C1-C4 alkoxy;
• e) substituted or unsubstituted phenyl;
• f) substituted or unsubstituted benzyl;
• g) carbocyclic;
• h) heterocyclic;
• i) and mixtures thereof;
• each Z is independently
• a) hydrogen;
• b) hydroxyl;
• c) halogen;
• d) —(CH2)mR;
• wherein R is:
• i) hydrogen;
• ii) hydroxyl
• iii) halogen;
• iv) nitrilo;
• v) —OR3;
• vi) —O(CH2)nN(R3)2;
• vii) —O(CH2)n+(R3)3X−;
• viii) —OCO(CH2)nN(R3)2;
• ix) —OCO(CH2)nN+(R3)3X−;
• x) —NHCO(CH2)nN(R3)2;
• xi) —NHCO(CH2)nN+(R3)3X−;
• xii) —(CH2)nN(R3)2;
• xiii) —(CH2)nN+(R3)3X−;
• xiv) carbocyclic;
• xv) heterocyclic;
• xvi) nitrogen heterocycle quaternary ammonium;
• xvii) nitrogen heterocycle N-oxide;
• xviii) aromatic N-heterocyclic quaternary ammonium;
• xix) aromatic N-heterocyclic N-oxide;
• xx) —NHCHO;
• xxi) or mixtures thereof;
• each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof;
• X is a water soluble anion;
• the index n is from 0 to 6
• e) —(CH2)mCOR′
• wherein R′ is
• i) —OR3;
• ii) —O(CH2)nN(R3)2;
• iii) —O(CH2)nN+(R3)3X−;
• iv) —NR3(CH2)nN(R3)2;
• v) —NR3(CH2)nN+(R3)3X−;
• vi) —(CH2)nN(R3)2;
• vii) —(CH2)nN+(R3)3X−;
• viii) or mixtures thereof;
• each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof;
• X is a water soluble anion;
• the index n is from 0 to 6;
• f) and mixtures thereof;
• the index m is from 0 to 6;
• II) cyclic units derived from cyclically polymerizing monomers having the formula:
• wherein each R4 is independently an olefin comprising unit which is capable of propagating polymerization in addition to forming a cyclic residue with an adjacent R4 unit;
• R5 is C1-C12 linear or branched alkyl, benzyl, substituted benzyl, and mixtures thereof;
• X is a water soluble anion;
• and
• III) mixtures thereof;
• provided said polymer or co-polymer has a net cationic charge;
• b) from 0.01% to 50% by weight, of a polyamine, said polyamine is selected from the group consisting of N,N′-bis(aminopropyl)-1,3-propylenediamine;
• N,N′-bis(hydroxyethyl)-N,N′-bis[3-N,N-bis(hydroxyethyl)aminopropyl]-1,3-propylenediamine;
• N,N′-bis(2-hydroxypropyl)-N,N′-bis[3-N,N-bis(2-hydroxypropyl)aminopropyl]-1,3-propylenediamine;
• N,N′-bis(2-hydroxybutyl)-N,N′-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-1,3-propylenediamine;
• 5-N-methyl dipropylenetriamine;
• 1,1-N-dimethyl-5-N′-methyl-9,9-N″-dimethyl dipropylenetriamine;
• 1,1-N-dimethyl-9,9-N″-dimethyl dipropylenetriamine;
• and mixtures thereof;
• c) from 0.005% to 1% by weight, of one or more crystal growth inhibitors;
• d) from 0.001% to 90% by weight, of one or more dye fixing agents;
• and
• e) the balance carriers and adjunct ingredients.

A composition providing dye protection benefits to fabric comprising:

• a) from 0.05% by weight, of a copolymer having the formula:
• wherein Z1 has the formula:
• Z2 has the formula:
• x has the value of from 10 to 100,000;
• y has the value of from 10 to 100,000;
• the ratio of x to y is from 9:1 to 1:9;
• B) a polyamine selected from the group consisting of N,N′-bis(aminopropyl)-1,3-propylenediamine, N,N′-bis(hydroxyethyl)-N,N′-bis[3-N,N-bis(hydroxyethyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxypropyl)-N,N′-bis[3-N,N-bis(2-hydroxypropyl)aminopropyl]-1,3-propylenediamine, N,N′-bis(2-hydroxybutyl)-N,N′-bis[3-N,N-bis(2-hydroxybutyl)aminopropyl]-1,3-propylenediamine, 5-N-methyl dipropylenetriamine, 1,1-N-dimethyl-5-N′-methyl-9,9-N″-dimethyl dipropylenetriamine, 1,1-N-dimethyl-9,9-N″-dimethyl dipropylenetriamine, and mixtures thereof;
• and C) the balance carriers and adjunct ingredients.

A composition providing dye protection benefits to fabric comprising:

• A) from 0.05% by weight, of a polymer, copolymer, or mixtures thereof, said polymer or copolymer comprising one or more units selected from the group consisting of:
• I) linear polymer units having the formula:
• wherein each R1 is independently
• a) hydrogen;
• b) C1-C4 alkyl;
• c) substituted or unsubstituted phenyl;
• d) substituted or unsubstituted benzyl;
• e) carbocyclic;
• f) heterocyclic;
• g) and mixtures thereof;
• each R2 is independently
• a) hydrogen;
• b) halogen
• c) C1-C4 alkyl;
• d) C1-C4 alkoxy;
• e) substituted or unsubstituted phenyl;
• f) substituted or unsubstituted benzyl;
• g) carbocyclic;
• h) heterocyclic;
• i) and mixtures thereof;
• each Z is independently
• a) hydrogen;
• b) hydroxyl;
• c) halogen;
• d) —(CH2)mR;
• wherein R is:
• i) hydrogen;
• ii) hydroxyl
• iii) halogen;
• iv) nitrilo;
• v) —OR3;
• vi) —O(CH2)nN(R3)2;
• vii) —O(CH2)nN+(R3)3X−;
• viii) —OCO(CH2)nN(R3)2;
• ix) —OCO(CH2)nN+(R3)3X−;
• x) —NHCO(CH2)nN(R3)2;
• xi) —NHCO(CH2)nN+(R3)3X−;
• xii) —(CH2)nN(R3)2;
• xiii) —(CH2)nN+(R3)3X−;
• xiv) carbocyclic;
• xv) heterocyclic;
• xvi) nitrogen heterocycle quaternary ammonium;
• xvii) nitrogen heterocycle N-oxide;
• xviii) aromatic N-heterocyclic quaternary ammonium;
• xix) aromatic N-heterocyclic N-oxide;
• xx) —NHCHO;
• xxi) or mixtures thereof;
• each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof;
• X is a water soluble anion;
• the index n is from 0 to 6
• e) —(CH2)mCOR′
• wherein R′ is
• i) —OR3;
• ii) —O(CH2)nN(R3)2;
• iii) —O(CH2)nN+(R3)3X−;
• iv) —NR3(CH2)nN(R3)2;
• v) —NR3(CH2)nN+(R3)3X−;
• vi) —(CH2)nN(R3)2;
• vii) —(CH2)nN+(R3)3X−;
• viii) or mixtures thereof;
• each R3 is independently hydrogen, C1-C8 alkyl, C2-C8 hydroxyalkyl, and mixtures thereof;
• X is a water soluble anion;
• the index n is from 0 to 6;
• f) and mixtures thereof;
• the index m is from 0 to 6;
• II) cyclic units derived from cyclically polymerizing monomers having the formula:
• wherein each R4 is independently an olefin comprising unit which is capable of propagating polymerization in addition to forming a cyclic residue with an adjacent R4 unit;
• R5 is C1-C12 linear or branched alkyl, benzyl, substituted benzyl, and mixtures thereof;
• X is a water soluble anion;
• and
• E) mixtures thereof;
• provided said polymer or co-polymer has a net cationic charge;
• B) from 0.01% by weight, of a fabric abrasion reducing polymer, said fabric abrasion polymer comprising:
• i) at least one monomeric unit comprising an amide moiety;
• ii) at least one monomeric unit comprising an N-oxide moiety;
• iii) and mixtures thereof;
• C) optionally from 1% by weight, of a fabric softening active;
• D) optionally less than 15% by weight, of a principal solvent, said principal solvent has a ClogP of from 0.15 to 1;
• E) optionally from 0.001% to 90% by weight, of one or more dye fixing agents;
• F) optionally from 0.01% to 50% by weight, of one or more cellulose reactive dye fixing agents;
• G) optionally from 0.01% to 15% by weight, of a chlorine scavenger;
• H) 0.005% to 1% by weight, of one or more crystal growth inhibitors;
• I) optionally from 1% to 12% by weight, of one or more liquid carriers;
• J) optionally from 0.001% to 1% by weight, of an enzyme;
• K) optionally from 0.01% to 8% by weight, of a polyolefin emulsion or suspension;
• L) optionally from 0.01% to 0.2% by weight, of a stabilizer;
• M) optionally from 1% to 80% by weight, of a cationic surfactant;
• N) from 0.01% by weight, of one or more linear or cyclic polyamines which provide bleach protection;
• and
• O) the balance carriers and adjunct ingredients.