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US 6,641,967 B2Granted
Carrier for electrophotography, two component type developer, and image forming method
AssigneeCanon Kabushiki Kaisha
InventorsTsuyoshi Takiguchi, Kenji Okado, Tetsuya Ida
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Abstract
A carrier for electrophotography and a two component type developer using the carrier. The carrier is composed of magnetic particles of a magnetic ferrite component represented by Formula: (Fe2O3)X(MnO)Y(A)Z. An image forming method is also disclosed which uses the two component type developer.
Claims16
An image forming method comprising:
- rotationally transporting a two component developer having a toner and a carrier, onto a developer carrying member;
- and
- developing in a developing zone an electrostatic latent image held on an electrostatic latent image bearing member with the toner of the two component developer carried on the developer carrying member, wherein said two component developer comprises (i) a negatively chargeable toner having toner particles and external additive and (ii) a carrier comprising magnetic carrier core particles and a resin coat layer comprising
- a silicone resin coating the magnetic carrier core particles, said carrier having a weight average particle diameter from 10 to 45 μm and a saturation magnetization from 20 Am2/kg to 70 Am2/kg, wherein:
- said toner particles comprise a colorant and a binder resin having a polyester resin, said polyester resin being prepared by co-condensing an etherified bisphenol with a mixture comprising a dibasic carboxylic acid and a tribasic or higher carboxylic acid, said tribasic or higher carboxylic acid present in amounts from 0.1 to 10 mole % based on the total moles of the components for preparing the polyester resin,
- said negatively chargeable toner has an acid value from 1 KOH mg/g to 20 KOH mg/g, a glass transition temperature (Tg) from 45° C. to 70° C. and a weight average particle diameter from 1 to 9 μm,
- said external additive comprises inorganic fine particles having been subjected to hydrophobic treatment and having a number average particle diameter from 0.005 μm to 0.2 μm;
- and
- said magnetic carrier core particles are formed of a magnetic ferrite component represented by the following Formula (I):
- (Fe2O3)x(MnO)Y(A)Z Formula (I)
- wherein A represents a member selected from the group consisting of Na2O, K2O, CaO, SrO and mixtures thereof;
- and x, y and z each represent a molar fraction and satisfy the condition of:
- 0.3<x<0.8, 0.01<Y<0.5, 0.06≦z≦0.16, x+y+z≦1.
10 more elements
Dependencies are inferred from the claim text.