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US 6,638,960 B2Granted
Halogenobenzimidazoles and their use as microbicides
AssigneeBayer Aktiengesellschaft
InventorsLutz Assmann, Albrecht Marhold, Ralf Tiemann, Klaus Stenzel
Life of this patent
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Abstract
New halogenobenzimidazoles of the formula in which A, R1, R2, R3, R4 and X have the meanings given in the description, and their acid addition salts and metal salt complexes, a process for their preparation and their use as microbicides in crop protection and in the protection of materials. New intermediates of the formulae in which R12-R17 and X have the meanings given in the description, and processes for the preparation of these substances.
Claims5
A halogenobenzimidazole of the formula:
- in which
- R1, R2, R3 and R4 independently of one another represent hydrogen, fluorine, chlorine, bromine, iodine, cyano, nitro, straight-chain or branched alkyl having 1 to 8 carbon atoms, straight-chain or branched halogenoalkyl having 1 to 6 carbon atoms and 1 to 13 identical or different halogen atoms, straight-chain or branched alkoxy having 1 to 8 carbon atoms, straight-chain or branched halogenoalkoxy having 1 to 6 carbon atoms and 1 to 13 identical or different halogen atoms, straight-chain or branched alkylthio having 1 to 8 carbon atoms, straight-chain or branched halogenoalkylthio having 1 to 6 carbon atoms and 1 to 13 identical or different halogen atoms, or represent -Z-R5,
- R5 represents aryl having 6 to 10 carbon atoms, it being possible for aryl to be monosubstituted to trisubstituted by identical or different substituents selected from the group consisting of halogen, cyano, nitro, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 atoms, alkylthio having 1 to 4 carbon atoms, halogenoalkyl having 1 to 4 carbon atoms and 1 to 5 identical or different halogen atoms, halogenoalkoxy having 1 to 4 carbon atoms and 1 to 5 identical or different halogen atoms, halogenoalkylthio having 1 or 4 carbon atoms atoms 1 to 5 identical or different halogen atoms, alkylsulphinyl having 1 to 4 carbon atoms, alkylsulphonyl having 1 to 4 carbon atoms, halogenoalkylsulphinyl having 1 to 4 carbon atoms and 1 to 5 identical or different halogen atoms and halogenoalkylsulphonyl having 1 to 4 carbon atoms and 1 to 5 identical or different halogen atoms,
- Z represents O or S,
- X represents fluorine, chlorine, bromine or iodine, and
- A represents the group —SO2—R8, wherein
- R8 denotes 1-pyrrolidinvl, it being possible for the 1-pyrrolidinyl to be monosubstituted to trisubstituted by identical or different substitutents selected from the group consisting of fluorine, chlorine, bromine, methyl, ethyl, n-or i-propyl and/or trifluoromethyl,
- or an acid addition salt or metal salt complex thereof.
5 more elements
Dependencies are inferred from the claim text.