Mineral-filled elastomer compositions
AssigneeCrompton Corporation
InventorsRichard W. Cruse, Martin J. Hannon, Prashant G. Joshi, Frederick D. Osterholtz, Robert J. Pickwell
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Abstract
A composition of matter is disclosed wherein the composition comprises: A) at least one latent mercaptosilane coupling agent; and B) at least one additional mercaptan. Preferably, the composition comprises: A) at least one sulfur vulcanizable rubber; B) at least one latent mercaptosilane coupling agent; C) at least one latent mercaptosilane activator; D) at least one filler; and, optionally, E) at least one additional mercaptosilane. A two pass process for preparing cured articles, such as tires and/or tire treads, which employs the composition is also disclosed.
Claims15
A process for the preparation of a rubber composition consisting essentially of the steps of:
- A) thermomechanically mixing in a first pass:
- 1) at least one sulfur vulcanizable rubber;
- 2) at least one latent mercaptosilane coupling agent;
- 3) at least one filler;
- and
- 4) at least one additional mercaptan, said additional mercaptan being a mercaptosilane selected from the group consisting of compounds of the structure
- (HS—)rG(—SiX3)t;
- B) bringing the temperature of the first pass mix from about 140° C. to about 200° C. over a period of 1 to 20 minutes;
- thereby forming a nonproductive first mixture;
- C) thermomechanically mixing the nonproductive first mixture in a second pass, optionally in the presence of at least one curing agent, at a temperature of from about 25 to about 100° C. for a period of from about 1 to about 30 minutes;
- thereby forming a productive second mixture;
- D) adding at least one latent-mercaptosilane activator in step A), step C), or both step A) and step C);
- E) shaping the second mixture;
- and then
- F) curing the second mixture at a temperature between about 130° C. to about 200° C. for a period of from about 5 to about 60 minutes.
Dependencies are inferred from the claim text.