Method for reducing gasoline sulfur in fluid catalytic cracking
AssigneesMobil Oil Corporation, W. R. Grace & Co.-Conn.
InventorsNazeer A. Bhore, Arthur W. Chester, Ke Liu, Hye Kyung Cho Timken
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AssigneesMobil Oil Corporation, W. R. Grace & Co.-Conn.
InventorsNazeer A. Bhore, Arthur W. Chester, Ke Liu, Hye Kyung Cho Timken
Estimating the term…
The sulfur content of liquid cracking products, especially the cracked gasoline, of a catalytic cracking process is reduced by the use of a catalyst having a product sulfur reduction component containing a metal component in an oxidation state greater than zero, wherein the average oxidation state of the metal component is increased by an oxidation step following conventional catalyst regeneration. The catalyst is normally a molecular sieve such as a zeolite Y, REY, USY, REUSY, Beta or ZSM-5. The metal component is normally a metal of Groups 5, 7, 8, 9, 12 or 13 of the periodic table, preferably vanadium or zinc. The sulfur reduction component may be a separate particle additive or part of an integrated cracking/sulfur reduction catalyst. A system for increasing the oxidation state of the metal component of a Gasoline Sulfur Reduction additive is also provided.
In a catalytic cracking process for cracking a hydrocarbon feed containing organosulfur compounds in the presence of a hot regenerated cracking catalyst, said process having a standpipe and/or standpipe cone located between a regenerator and a riser and said catalyst having a product sulfur reduction component comprising a matrix of alumina or silica-alumina with clay and containing a cracking component comprising a zeolite which contains within its interior pore structure a metal component comprising vanadium in an oxidation state greater than zero, the improvement which comprises:
In a catalytic cracking process for cracking a hydrocarbon feed containing organosulfur compounds in the presence of a hot regenerated cracking catalyst, said catalyst having a product sulfur reduction component comprising a matrix of alumina or silica-alumina with clay and containing a cracking component comprising a zeolite which contains within its interior pore structure a metal component comprising vanadium in an oxidation state greater than zero, the improvement which comprises:
Dependencies are inferred from the claim text.