Flame-retardant resin, composition thereof, and process for producing the same
AssigneeOtsuka Kagaku Kabushiki Kaisha
InventorsYuji Tada, Yoichi Nishioka, Tadao Yabuhara, Takashi Kameshima, Shinji Nakano
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Abstract
A flame-retardant resin composition comprising a phosphazene flame retardant and a polyester resin, wherein the flame retardant is bonded to the molecules of the polyester resin via the ester group thereof, can retain a high flame retardance for a prolonged term with little or no vaporization with time and is excellent in flame retardance, impact resistance, properties and processability.
Claims5
A flame-retardant resin composition, comprising a phosphazene flame retardant and a polyester resin, wherein the flame retardant is bonded to the polyester resin by an ester group thereof, wherein the phosphazene flame retardant is a phosphazene of formula (I)
- wherein
- n is an integer,
- X and Y are independently, O, S, NH or NR3, wherein R3 is an alkyl group having 1 to 4 carbon atoms,
- at least one of R1 and R2, which are n in number, is a group selected from the group consisting of formula (2)
- and the remaining R1 and R2 groups are independently, a group selected from the group consisting of formula (3)
- wherein
- each of R4, R6 and R7 is a hydrogen atom or alkyl group having 1 to 4 carbon atoms,
- R5 is an alkyl group having 1 to 4 carbon atoms,
- m is an integer of 1 to 10, and
- n is an integer of 3 to 25 when the phosphazene is a cyclic compound, or an integer of 3 to 1000 when the phosphazene is a straight-chain compound.
A flame-retardant resin comprising a phosphazene flame retardant and a polycarbonate resin, wherein the flame retardant is bonded to molecules of the polycarbonate resin by an ester group thereof.
A flame retardant resin comprising a phosphazene flame retardant and a polycarbonate resin, wherein the flame retardant resin is obtained by an ester exchange reaction between the flame retardant and the polycarbonate resin in an amount of 0.1 to 100 parts by weight per 100 parts by weight of the polycarbonate resin.
A process for preparing a flame-retardant resin comprising a phosphazene flame retardant and a polyester resin, the process comprising conducting an ester exchange reaction between the flame retardant and the polyester resin in a molten state, wherein the phosphazene is free of halogen atoms.
A process for preparing a flame-retardant resin comprising a phosphazene flame retardant and a polyester resin, the process comprising conducting an ester exchange reaction between the flame retardant and the polyester resin in a molten state, wherein the phosphazene flame retardant is at least one species selected from the group of cyclic phosphazene compounds and straight-chain phosphazene compounds of formula (I)
- wherein
- n is an integer,
- X and Y are independently, O, S, NH, and NR3, wherein R3 is an alkyl group having 1 to 4 carbon atoms,
- at least one R1 and R2, which are n in number, is a group selected from the group consisting of formula (2)
- and the remaining R1 and R2 groups are independently, a group selected from the group consisting of formula (3)
- wherein
- each of R4, R6 and R7 is a hydrogen atom or alkyl group having 1 to 4 carbon atoms,
- R5 is an alkyl group having 1 to 4 carbon atoms,
- m is an integer of 1 to 10, and
- n is an integer of 3 to 25 when the phosphazene is a cyclic compound, or an integer of 3 to 1000 when the phosphazene is a straight-chain compound.
Dependencies are inferred from the claim text.