Alkyd-based ink vehicles and ink compositions
OwnerRaymond H. Jones, Thomas C. Jordaninventors
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Abstract
The specification discloses improved alkyd-based ink vehicles for lithographic inks. An ink vehicle according to the invention may contain a rosin ester resin, an ink solvent and from about 1 to about 30% by weight alkyd resin comprising the reaction product of a monounsaturated cyclic diacid anhydride, a polyol and a tall oil fatty acid. The ink vehicle enables faster ink drying and improved pigment wetting without significant adverse affects on other properties of ink formulations such as misting and volatility.
Claims24
An ink vehicle which comprises a primary resin selected from the group consisting of rosin esters, phenolic modified rosin esters, maleic modified rosin esters, hydrocarbon resins, and modified hydrocarbon resins, an ink solvent having a boiling point of from about 180° C. to about 535° C., and from about 1 to about 30% by weight of an alkyd resin having a Gardner-Holdt viscosity of from about Z6.0 to about Z7.5 and an acid number less than about 5, the alkyd resin consisting essentially of the reaction product of 1,2,3,6-tetrahydrophthalic anhydride, a polyol selected from the group consisting of glycerol, trimethylolethane, trimethylolpropane, and dimethylolpropane,and a tall oil acid.
A method for making an ink vehicle consisting essentially of reacting 1,2,3,6-tetrahydrophthalic anhydride, a polyol selected from the group consisting of glycerol trimethylolethane, trimethylolpropane, and dimethylolpropane, and a tall oil fatty acid under conditions sufficient to produce an alkyd resin having a Gardner-Holdt viscosity of from about Z6.0 to about Z7.5 and an acid number less than about 5, and mixing from about 1 to about 30 wt. % of the alkyd resin with a primary resin selected from the group consisting of rosin esters, phenolic modified rosin esters, maleic modified rosin esters, hydrocarbon resins, and modified hydrocarbon resins, an ink solvent having a boiling point of from about 180° C. to about 535° C. and, optionally, a metallic gelling agent.
An ink composition comprising pigment and from about 45 to about 65% by weight of an ink vehicle, the ink vehicle comprising a primary resin selected from the group consisting of gum rosin, tall oil rosin, and wood rosin esters and esters dimerized rosins, an ink solvent having a boiling point of from about 180° C. to about 535° C., and from about 1 to about 30% by weight of an alkyd resin consisting essentially of the reaction product of 1,2,3,6-tetrahydrophthalic anhydride, a polyol selected from the group consisting of glycerol, triethylolethane, trimethylolpropane, and dimethylolpropane, and a tall oil fatty acid, said alkyd resin having a Gardner-Holdt viscosity of from about Z6.0 to about Z7.5, and an acid number less than about 5.
A flushed pigment comprising pigment and from about 5 to about 15 wt. % alkyd resin consisting essentially of the reaction product of 1,2,3,6-tetrahydrophthalic anhydride, a polyol selected from glycerol, trimethylolethane, trimethylolpropane, and dimethylolpropane, and a tall oil fatty acid, said alkyd resin having a Gardner-Holdt viscosity of from about Z6.0 to about Z7.5, and an acid number less than about 5.
Dependencies are inferred from the claim text.