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US 6,632,380 B1Granted
Chemical compounds made of intrinsically conductive polymers and metals
AssigneeZipperling Kessler & Co. (GmbH & Co.)
InventorBernhard Wessling
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Abstract
Compounds of intrinsically conductive polymers, in particular polyanilines, with metals, their preparation and uses of these compounds are described.
Claims20
A compound corresponding to formula (I)
- [(DU)a−x(Mea+)x(DUoxH+)y](a·x+y)A− (I)
- wherein
- DU = a dimer unit of an intrinsically conductive polyaniline polymer, DUox = an oxidized form of the dimer unit, Mea+ = a metal ion of valency a, selected from the group consisting of iron, copper, zinc, and magnesium, a = the valency of the metal ion, x = an integer from 1 to 10,000, y = an integer from 0 to 10,000, A− = an anion.
A compound corresponding to formula (I)
- [(DU)a−x(Mea+)x(DUoxH+)y](a·x+y)A− (I)
- wherein
- DU = a dimer unit of an intrinsically conductive polyaniline polymer, DUox = an oxidized form of the dimer unit, Mea+ = a metal ion of valency a, selected from the group consisting of iron, copper, zinc, and magnesium, a = the valency of the metal ion, x = an integer from 1 to 10,000, y = an integer from 0 to 10,000, and A− = an anion,
- (a) contacting a dispersion of said intrinsically conductive polymer with the chosen metal Mea+ in elemental form;
- (b) agitating the dispersion medium in order to ensure exchange of matter at the interface between the metal and dispersion, and
- (c) maintaining the dispersion in contact with the metal until said compound has formed.
3 more elements
Process for the preparation of a compound comprising a metal chemically bonded to an intrinsically conductive polymer comprising
- (a) contacting a dispersion of an intrinsically conductive polyaniline polymer with the iron, copper, zinc or magnesium metal in elemental form,
- (b) agitating the dispersion medium in order to ensure exchange of matter at the interface between the metal and dispersion, and
- (c) maintaining the dispersion in contact with the metal until said compound has formed.
Dependencies are inferred from the claim text.