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US 6,624,321 B2Granted
Process for the preparation of polyether polyols
AssigneeBayer Aktiengesellschaft
InventorsUwe Denninger, Jörg Hofmann, Pramod Gupta
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Abstract
The present invention relates to a process for the preparation of polyether polyols by the reaction of alkylene oxides and compounds containing active hydrogens, in the presence of specific Lewis acid metal compounds as catalysts, novel bis(perfluoroalkylsulfonic acid) compounds of Group 13 of the Periodic Table of the Elements, and to a process for the preparation thereof and the use thereof as catalysts for ring-opening polymerization of cyclic ethers.
Claims10
A compound corresponding to the formula (XI)
- (RFSO3)2M(ERE′I) (XI)
- wherein:
- RF:
- represents a perfluoroalkyl or perfluoroaryl group;
- M:
- represents a metal from Group 13 of the Periodic Table of the Elements;
- E:
- represents oxygen, sulfur, selenium, NR1 or PR1,
- wherein:
- R1:
- represents a hydrogen atom or a C1-C20 hydrocarbon radical which may be alkyl or aryl, wherein R1 can form a ring with R;
- R:
- represents a C1-C30 hydrocarbon bridge which may be an alkylene, arylene or aralkylene bridge;
- E′:
- represents a hydrogen atom, a C1-C20 hydrocarbon radical which may be alkyl or aryl, OR2, NR2R3, halogen, SR2 or PR2R3,
- wherein:
- R2 and R3:
- may be the same or different and each represents a hydrogen atom, or a C1-C20 hydrocarbon radical which may be alkyl, aryl or aralkyl, wherein R2 can form a ring with R3 or R and/or R3 can form a ring with R or R2, and
- I:
- represents an integer from 1 to 10.
17 more elements
Dependencies are inferred from the claim text.