Fertilizer encapsulation using sulfur containing polyols
AssigneeBayer Aktiengesellschaft
InventorsPeter H. Markusch, Robert L. Cline
Life of this patent
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Abstract
This invention relates to fertilizer encapsulation with polyurethanes wherein the isocyanate-reactive composition contains sulfur. The process of the present invention comprises applying a polyisocyanate composition to fertilizer particles, applying an isocyanate-reactive composition which contains sulfur to the polyisocyanate coated fertilizer particles, or applying an isocyanate-reactive composition which contains sulfur to fertilizer particles and then applying a polyisocyanate composition to the isocyanate-reactive coated fertilizer particles, and repeating these steps as necessary to form sulfur containing polyurethane encapsulated fertilizer particles.
Claims16
A process for the production of an encapsulated, slow release fertilizer composition comprising:
- 1) applying a polyisocyanate composition to fertilizer particles which contain at least one water soluble plant nutrient to form isocyanate coated fertilizer particles
- 2) applying an isocyanate-reactive composition containing from 2 to 4 hydroxyl groups capable of reacting with the NCO groups of the isocyanate component, and having a molecular weight of about 106 to about 400, an equivalent weight of about 31 to less than about 100, and containing 30 to 80% by weight of sulfur based on 100% by weight of said isocyanate reactive composition, to the isocyanate coated fertilizer particles from step 1) to yield polyurethane encapsulated fertilizer particles;
- and
- 3) repeating steps 1) through 2) as many times as necessary, wherein the encapsulated fertilizer particles from step 2) are substituted for the fertilizer particles in step 1) above;
- thereby forming encapsulated fertilizer particles which contain from about 2 to 20% by weight of sulfur containing polyurethane, based on the total weight of the encapsulated fertilizer particles, wherein the polyurethane encapsulation contains at least 5% by weight of sulfur.
A process for the production of an encapsulated, slow release fertilizer composition comprising:
- 1) applying an isocyanate-reactive composition to fertilizer particles which contain at least one water soluble plant nutrient to form fertilizer particles coated with the isocyanate-reactive composition, wherein said isocyanate-reactive composition has a functionality of 2 to 8, a molecular weight of about 200 to about 1600, an equivalent weight of at least about 100 to less than about 200, and containing 30 to 80% by weight of sulfur based on 100% by weight of said isocyanate reactive composition;
- 2) applying a polyisocyanate composition to the coated fertilizer particles from step 1) to yield polyurethane encapsulated fertilizer particles;
- and
- 3) repeating steps 1) through 2) as many times as necessary, wherein the encapsulated fertilizer particles from step 2) are substituted for the fertilizer particles in step 1) above;
- thereby forming encapsulated fertilizer particles which contain from about 2 to 20% by weight of sulfur containing polyurethane, based on the total weight of the encapsulated fertilizer particles, wherein the polyurethane encapsulation contains at least 5% by weight of sulfur.
Dependencies are inferred from the claim text.