A work having a vapor deposited film formed thereon from at least one metal selected from the group consisting of aluminum, titanium, zinc, tin, lead and bismuth by a surface treating process for forming a vapor deposited film from an easily oxidizable vapor-depositing material on the surface of the work, comprising the step of evaporating the vapor-depositing material in a state in which a vapor deposition controlling gas has been supplied to at least zones near a material melting/evaporating source and the work within a treating chamber such that said vapor deposited film contains hydrogen in a range from 1 ppm to 20 ppm.