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US 6,610,811 B1Granted
Polyurethanes with improved tear propagation resistance
AssigneeHenkel Kommanditgesellschaft auf Aktien
InventorsAlfred Westfechtel, Roland Gruetzmacher, Rainer Hoefer
Life of this patent
Estimating the term…
Abstract
Polyurethanes having improved tear resistance which are the reaction product of the following components: A) a polyol component containing dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols and B) an isocyanate component containing prepolymers obtained by reacting polyfunctional isocyanates with dimer diol and/or trimer triol and/or an OH-terminated polyester produced from polycarboxylic acids, preferably dimer fatty acid and/or trimer fatty acid, and diols; and processes for their manufacture.
Claims32
A polyurethane which is a reaction product consisting of the following components:
- A) a polyol component, wherein the polyol component consists of from about 50 to about 90% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and the balance of the weight of the polyol component consisting of at least one compound selected from the group consisting of polyethers, polyesters, and oleochemical polyols;
- and
- B) an isocyanate component, said isocyanate component consisting of a polyurethane prepolymer which is the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1;
- and wherein the tear propagation resistance of the polyurethane is greater than 10 Nmm−1.
2 more elements
A polyurethane which is a reaction product consisting of the following components:
- A) a polyol component, wherein the polyol component consists of from about 50% to 100% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and wherein any balance of the weight of the polyol component consists of at least one compound selected from the group consisting of polyethers, polyesters, and oleochemical polyols;
- and
- B) an isocyanate component, said isocyanate component consisting of a polyurethane prepolymer which is the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1;
- and wherein at least one of components A) and B) contains an OH-terminated polyester selected from the group consisting of adipic acid, phthalic acid, maleic acid, and azelaic acid.
2 more elements
A polyurethane which is a reaction product comprised of the following components:
- A) a polyol component, wherein the polyol component consists of from about 50 to about 90% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters comprising polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and the balance of the weight of the polyol component consisting of at least one polyether compound which is an alkoxylation product of a dimer diol or a trimer triol containing from 1 to 20 moles of alkylene oxide per mole of dimer diol or trimer triol;
- and
- B) an isocyanate component, said isocyanate component comprising a polyurethane prepolymer comprising the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters comprising polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1.
1 more element
A process for the manufacture of a polyurethane comprising reacting together the following components:
- A) a polyol component, wherein the polyol component consists of from about 50 to about 90% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and the balance of the weight of the polyol component consisting of at least one compound selected from the group consisting of polyethers, polyesters, and oleochemical polyols;
- and
- B) an isocyanate component, said isocyanate component consisting of polyurethane prepolymer which is the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1;
- and wherein the tear propagation resistance of the polyurethane is greater than 10 Nmm−1.
2 more elements
A process for the manufacture of a polyurethane comprising reacting together reactants consisting of the following components:
- A) a polyol component, wherein the polyol component consists of from about 50% to 100% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and wherein any balance of the weight of the polyol component consists of at least one compound selected from the group consisting of polyethers, polyesters, and oleochemical polyols;
- and
- B) an isocyanate component, said isocyanate component consisting of a polyurethane prepolymer which is the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1;
- and wherein at least one of components A) and B) contains an OH-terminated polyester selected from the group consisting of adipic acid, phthalic acid, maleic acid, and azelaic acid.
2 more elements
A process for the manufacture of a polyurethane comprising reacting together reactants consisting of the following components:
- A) a polyol component, wherein the polyol component consists of from about 50 to about 90% by weight of at least one subcomponent selected from the group consisting of dimer diols, trimer triols, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units, wherein the polycarboxylic acid units are dimer or trimer fatty acid units, and the balance of the weight of the polyol component consisting of at least one compound selected from the group consisting of polyethers, polyesters, and oleochemical polyols;
- and
- B) an isocyanate component, said isocyanate component consisting of polyurethane prepolymer which is the reaction product of a polyfunctional isocyanate and at least one compound selected from the group consisting of dimer diols, trimer triols, polyethers containing dimer diol units, and OH-terminated polyesters, said OH-terminated polyesters consisting of polycarboxylic acid units and diol units;
- wherein the ratio of isocyanate groups in B) to hydroxyl groups in A) is from about 0.95:1 to about 1.05:1.
1 more element
Dependencies are inferred from the claim text.