Flame retardant polybutyleneterephthalate resin
AssigneeKolon Industries, Inc.
InventorsYoung-Ik Seo, Chung-Seock Kang, Tae-Gun Choi, Jun-Myoung Song
Life of this patent
Estimating the term…
Abstract
Disclosed is a flame retardant polybutyleneterephthalate resin prepared be copolymerizing a phosphorus-based flame retardant represented by the following formula I and a butyleneterephthalate unit: wherein R1 and R2 are different or the same and are methyl or butyl including a hydroxyl group.
Claims26
A flame retardant polybutyleneterephthalate resin prepared by:
- (a) performing a transesterification reaction of a dicarboxylic acid or its ester derivative and a 1,4-butanediol to yield an oligomer;
- (b) reacting the oligomer with 0.5 to 30 parts by weight of a phosphorus-based flame retardant represented by the following formula I with respect to 100 parts by weight of the dicarboxylic acid or its ester derivative;
- and
- (c) performing a polycondensation reaction in the presence of a polycondensation catalyst to prepare a polybutyleneterephthalate:
- wherein R1 and R2 are same or different and are methyl or butyl including a hydroxyl group.
A flame retardant polybutyleneterephthalate resin prepared by:
- (a) performing a transesterification reaction of a dicarboxylic acid or its ester derivative and a 1,4-butanediol to yield an oligomer;
- (b) reacting the oligomer with 0.5 to 30 parts by weight of a phosphorus-based flame retardant represented by the following formula I with respect to 100 parts by weight of the dicarboxylic acid or its ester derivative and
- (c) adding a deposited particle-forming material or an inorganic particle material and performing a polycondensation reaction in the presence of a polycondensation catalyst to prepare a polybutyleneterephthalate:
- wherein R1 and R2 are different or the same and are methyl or butyl including a hydroxyl group.
A flame retardant polybutyleneterephthalate resin composition comprisinig 50 to 90 wt. % of a polybutyleneterephthalate resin and 10 to 50 wt. % of a reinforcing material.
- the polybutyleneterephthalate resin being prepared by:
- (a) performing a transesterification reaction of a dicarboxylic acid or its ester derivative and a 1,4-butanediol to yield an oligomer;
- (b) reacting the oligomer with 0.5 to 30 parts by weight of a phosphorus-based flame retardant represented by the following formula I with respect to 100 parts by weight of the dicarboxylic acid or its ester derivative;
- and
- (c) performing a polycondensation reaction in the presence of a polycondensation catalyst to prepare a polybutyleneterephthalate,
- wherein the polybutyleneterephthalate resin has an Izod impact strength of more than 3 kg·cm/cm, a tensile strength of more than 400 kg/cm2 and a tensile elongation of more than 10%:
- wherein R1 and R2 are different or the same and are methyl or butyl including a hydroxyl group.
Dependencies are inferred from the claim text.