Adhesive compositions with reduced coefficient of friction

A two-phase polymerizable monomeric adhesive composition, comprising:

• a first phase comprising a 1,1-disubstituted ethylene monomer;
• and
• a second phase comprising a slip additive,
• wherein said second phase is soluble in said first phase but said second phase is insoluble or substantially insoluble in a polymer formed from said monomer, and
• wherein the slip additive is selected from the group consisting of siloxane-containing monomers;
• siloxane-containing copolyols;
• fluorinated siloxanes;
• a fluorinated α-cyanoacrylate monomers;
• siloxane-containing copolyols;
• fluorinated siloxanes;
• a fluorinated α-cyanoacrylate monomer;
• a fluorinated cyanopentadienoate;
• a fluorinated polycyanpacrylate;
• a fluorinated polymer selected from the group consisting of ethylene-chlorotrifluoroethylene coploymer, ethylene-tetrafluoroethylene, tetrafluoroethylene, polytetrafluoroethylene, polytetrafluoroethylene fluorinated ethylene propylene, polytetrafluoroethylene perfluoroalkoxy, and polyvinylidene fluoride;
• and a fluorine-containing compound of the following general formula:
• wherein m, n and p are independently intergers of from about 1 to about 20, x is independently an integer of from 1 to m, y is independently an interger of from 1 to n, and z is independently an interger of from 1 to p.

A two-phase polymerizable monomeric adhesive composition, comprising:

• a first phase comprising a 1,1-disubstituted ethylene monomer;
• and
• a second phase comprising a slip additive,
• wherein said second phase is soluble in said 1,1-disubstituted ethylene monomer but is insoluble or substantially insoluble in said polymer, and
• wherein the slip additive is selected from the group consisting of siloxane-containing monomers;
• siloxane-containing copolyols;
• fluorinated siloxanes;
• a fluorinated α-cyanoacrylate monomer;
• a flourinated cyanopentadienoate;
• a fluorinated polycyanpacrylate;
• a fluorinated polymer selected from the group consisting of ethylene-chlorotrifluoroethylene coploymer, ethylene-tetrafluoroethylene, tetrafluoroethylene, polytetrafluoroethylene, polytetrafluoroethylene fluorinated ethylene propylene, polytetrafluoroethylene perfluoroalkoxy, and polyvinylidene fluoride;
• and a fluorine-containing compound of the following general formula:
• wherein m, n and p are independently intergers of from about 1 to about 20, x is independently an integer of from 1 to m, y is independently an interger of from 1 to n, and z is independently an interger of from 1 to p.

A polymerizable monomer adhesive composition, comprising:

• a 1,1-disubstituted ethylene monomer;
• and
• at least one slip additive,
• wherein said slip additive causes a polymer film formed from said monomer to have a lower coefficient of friction than in an absence of said slip additive, and
• wherein the coefficient of friction is lowered by at least 30%.