Flame retardant polycarbonate resin/ABS graft copolymer blends
AssigneeGeneral Electric Company
InventorsKirk J. Blackburn, Robert R. Gallucci, Emil M. Georgiev
Life of this patent
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Abstract
A thermoplastic resin composition contains an aromatic carbonate resin, a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and a flame retarding amount of an alkali metal or alkaline earth metal salt of an alkylbenzenesulfonic acid flame retardant.
Claims32
A thermoplastic resin composition, comprising:
- (a) an aromatic carbonate resin,
- (b) a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase and wherein the rigid thermoplastic phase has a glass transition temperature of at least 25° C., and
- (c) a flame retarding amount of an alkali metal or alkaline earth metal salt of an aromatic sulfonic diacid having aromatic centers that have at least one electron donating group.
A thermoplastic resin composition, comprising the composition resulting from blending:
- (a) a polycarbonate resin,
- (b) a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and wherein the rigid thermoplastic phase has a glass transition temperature of at least 25° C., and
- (c) a flame retarding amount of an alkali metal or alkaline earth metal salt of an aromatic sulfonic diacid having aromatic centers that have at least one electron donating group.
A thermoplastic resin composition, comprising:
- (a) an aromatic carbonate resin,
- (b) a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase and wherein the rigid thermoplastic phase has a glass transition temperature of at least 25° C., and
- (c) a flame retarding amount of an alkali metal or alkaline earth metal salt of a sulfonic diacid having aromatic centers with at least one electron donating group, said compound having the formula:
- where R is independently for each substitution a one to forty carbon atom alkyl, aralkyl or aromatic group, M is a metal selected from the group of alkali metals and alkaline earth metals with x the oxidation state of the metal, M, where i, j, k and m are each integers ranging from 0 to 5 subject to the limitation that i+k is at least 1 and subject to the further limitation that i+j is less than or equal to 5 and k+m is less than or equal to 5.
A thermoplastic resin composition, comprising the composition resulting from blending:
- (a) a polycarbonate resin,
- (b) a rubber modified graft copolymer comprising a discontinuous rubber phase dispersed in a continuous rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is chemically grafted to the rubber phase, and wherein the rigid thermoplastic phase has a glass transition temperature of at least 25° C., and
- (c) a flame retarding amount of an alkali metal or alkaline earth metal salt of a sulfonic diacid having aromatic centers with at least one electron donating group, said compound having the formula:
- where R is independently for each substitution a one to forty carbon atom alkyl, aralkyl or aromatic group, M is a metal selected from the group of alkali metals and alkaline earth metals with x the oxidation state of the metal, M, where i, j, k and m are each integers ranging from 0 to 5 subject to the limitation that i+k is at least 1 and subject to the further limitation that i+j is less than or equal to 5 and k+m is less than or equal to 5.
Dependencies are inferred from the claim text.