Polyorganosiloxane compound and coating composition containing the same
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsHiroaki Kizaki, Masaaki Yamaya, Akinari Itagaki
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Abstract
A polyorganosiloxane compound obtained by allowing a polyorganosiloxane having silicone resin structure to react with a polyorganosiloxane having silicone oil structure in the presence of a hydrosilylation catalyst, and having the both structures in the molecule. Also disclosed is a coating composition including the polyorganosiloxane compound, a silane or silicone resin having an RO—Si group, and a curing catalyst. The former polyorganosiloxane compound is compatible with silicone resins. The latter coating composition can provide coatings improved in flexibility without lowering the curability, surface hardness and weatherability inherent in silicone resins.
Claims13
A polyorganosiloxane compound which contains in the molecule a silicone oil structure and a silicone resin structure having at least one alkoxyl group and is compatible with a silicone resin, said polyorganosiloxane being obtained by allowing the following polyorganosiloxane (a1):
- (a1) a polyorganosiloxane represented by the average compositional formula (1):
- R1aR2bSi(OR3)cO(4−a−b−c)/2 (1)
- wherein R1 is at least one member selected from the group consisting of a substituted or unsubstituted alkyl group and a substituted or unsubstituted aryl group;
- R2 is a group containing an aliphatic unsaturated double bond;
- R3 is an alkyl group having 1 to 4 carbon atoms which may have an ether linkage;
- and a, b and c are numbers that satisfy the following relation:
- 0≦a<1.5, 0.01≦b≦1, 0.5≦a+b≦1.8, 0.01≦c≦2.5 and 1≦a+b+c≦3;
- and having at least one aliphatic unsaturated double bond in the molecule, to react with the following polyorganosiloxane (a2):
- (a2) a polyorganosiloxane represented by the general formula (2):
- wherein R1 is as defined in the above formula (1), and n is a number of from 0 to 1,000, in the presence of a hydrosilylation catalyst.
Dependencies are inferred from the claim text.