1,2-bis(methyl(1,1,3,3-tetramethylbutyl)-phosphino)ethane, process the preparation thereof, transition metal complexes containing the same as a ligand and uses thereof
AssigneeNippon Chemical Industries Co., Ltd.
InventorsMasashi Sugiya, Hiroyuki Nohira
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Abstract
The present invention provides a novel bisphosphine compound having a chiral center on the phosphorus atom, which is suitable as a ligand for an asymmetric catalyst for use in asymmetric hydrogenation, this bisphosphine compound being represented by the following formula (1): (where t—C8H17 denotes 1,1,3,3-tetramethylbutyl), and a process for the production of this bisphosphine compound. Also provided are a transition metal complex having this bisphosphine compound as a ligand, and a process for the asymmetric hydrogenation of an unsubstituted carboxylic acid or its ester.
Claims7
A 1,2-bis(methyl(1,1,3,3-tetramethylbutyl)phosphino)-ethane represented by the following general formula (1):
- (where t—C8H17 denotes 1,1,3,3-tetramethylbutyl).
Dependencies are inferred from the claim text.