Tractions fluids having excellent low temperature properties
AssigneeDow Corning Corporation
InventorsKenneth Christopher Fey, Glenn Frederick Viaplana Gordon, Terrence Keith Hilty, Russell Keith King, Tina Marie Leaym, Gary Michael Wieber, Eugene Dale Groenhof
Life of this patent
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Abstract
Traction fluids suitable for operations under widely varying temperature environments, particularly having excellent low temperature properties are described. The tractions fluids comprise blends of organic oils and siloxane compositions. The siloxane compositions may include MTQ, MT, MQ, MDT, MDM, or D units in varying molar percents.
Claims16
A traction fluid comprising:
- (A) 15 to 99 weight percent of at least one organic oil;
- and
- (B) 1 to 85 weight percent of at least one siloxane composition chosen from;
- (I) 33 to 80 mole percent units of formula (R3SiO1/2), 0.2 to 66.8 mole percent units of formula (RSiO3/2), and 66.8 to 0.2 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 50,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (II) 33 to 75 mole percent units of formula (R3SiO1/2) and 67 to 25 mole percent units of formula (RSiO3/2) having a viscosity of from 2.0 to 20,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (III) 33 to 80 mole percent units of formula (R3SiO1/2) and 67 to 20 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 70,000 mPas at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not metbyl;
- and
- (VI) cyclosiloxanes of formula (R2SiO2/2)a having a viscosity of from 2.0 to 50,000 mPa.s at 40° C., where a is an integer ranging from 3 to 20, each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl.
A method of making a traction fluid comprising the step of mixing:
- (A) 15 to 99 weight percent of at least one organic oil;
- and
- (B) 1 to 85 weight percent of at least one siloxane composition chosen from;
- (I) 33 to 80 mole percent units of formula (R3SiO1/2), 0.2 to 66.8 mole percent units of formula (RSiO3/2), and 66.8 to 0.2 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 50,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (II) 33 to 75 mole percent units of formula (R3SiO1/2) and 67 to 25 mole percent units of formula (RSiO3/2) having a viscosity of from 2.0 to 20,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (III) 33 to 80 mole percent units of formula (R3SiO1/2) and 67 to 20 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 70,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- and
- (VI) cyclosiloxanes of formula (R2SiO2/2)a having a viscosity of from 2.0 to 50,000 mPa.s at 40° C., where a is an integer ranging from 3 to 20, each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl.
A traction fluid comprising:
- (A) 15 to 99 weight percent of at least one organic oil other than unsaturated polybutene, unsaturated polyisobutylene, and hydrogenated polyisobutylene;
- and
- (B) 1 to 85 weight percent of at least one siloxane composition chosen from;
- (I) 33 to 80 mole percent units of formula (R3SiO1/2), 0.2 to 66.8 mole percent units of formula (RSiO3/2), and 66.8 to 0.2 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 50,000 mpa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (II) 33 to 75 mole percent units of formula (R3SiO1/2) and 67 to 25 mole percent units of formula (RSiO3/2) having a viscosity of from 2.0 to 20,000 mPas at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (III) 33 to 80 mole percent units of formula (R3SiO1/2) and 67 to 20 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 70,000 maP.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (IV) 0 to 28 mole percent units of formula (R3SiO/1/2), 37 to 93 mole percent units of formula (R2SiO2/2), and 6 to 56 mole percent units of formula (RSiO3/2) having a viscosity of from 5.0 to 10,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl and provided further that at least one of the R groups which is not methyl is chosen from alkyl groups comprising 7 to 18 carbon atoms and aryl groups comprising 7 to 18 carbon atoms;
- (V) 1 to 100 mole percent units of formula (R3SiO1/2) and 99 to 0 mole percent units of formula (R2SiO2/2) having a viscosity of from 1.0 to 50,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl and provided further that at least one of the R groups which is not methyl is chosen from alkyl groups comprising 7 to 18 carbon atoms and aryl groups comprising 7 to 18 carbon atoms;
- and
- (VI) cyclosiloxanes of formula (R2SiO2/2)a having a viscosity of from 2.0 to 50,000 mPa.s at 40° C., where a is an integer ranging from 3 to 20, each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl.
A method of making a traction fluid comprising the step of mixing:
- (A) 15 to 99 weight percent of at least one organic oil other than unsaturated polybutene, unsaturated polyisobutylene, and hydrogenated polyisobutylene;
- and
- (B) 1 to 85 weight percent of at least one siloxane composition chosen from;
- (I) 33 to 80 mole percent units of formula (R3SiO1/2), 0.2 to 66.8 mole percent units of formula (RSiO3/2), and 66.8 to 0.2 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 50,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (II) 33 to 75 mole percent units of formula (R3SiO1/2) and 67 to 25 mole percent units of formula (RSiO3/2) having a viscosity of from 2.0 to 20,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (III) 33 to 80 mole percent units of formula (R3SiO1/2) and 67 to 20 mole percent units of formula (SiO4/2) having a viscosity of from 1.0 to 70,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl;
- (IV) 0 to 28 mole percent units of formula (R3SiO/1/2), 37 to 93 mole percent units of formula (R2SiO2/2), and 6 to 56 mole percent units of formula (RSiO3/2) having a viscosity of from 5.0 to 10,000 rnPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl and provided further that at least one of the R groups which is not methyl is chosen from alkyl groups comprising 7 to 18 carbon atoms and aryl groups comprising 7 to 18 carbon atoms;
- (V) 1 to 100 mole percent units of formula (R3SiO1/2) and 99 to 0 mole percent units of formula (R2SiO2/2) having a viscosity of from 1.0 to 50,000 mPa.s at 40° C., where each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 70 mole percent of R groups are not methyl and provided further that at least one of the R groups which is not methyl is chosen from alkyl groups comprising 7 to 18 carbon atoms and aryl groups comprising 7 to 18 carbon atoms;
- and
- (VI) cyclosiloxanes of formula (R2SiO2/2)a having a viscosity of from 2.0 to 50,000 mPa.s at 40° C., where a is an integer ranging from 3 to 20, each R is independently selected from alkyl groups comprising 1 to 18 carbon atoms and aryl groups comprising 6 to 18 carbon atoms provided from 10 to 7b mole percent of R groups are not methyl.
Dependencies are inferred from the claim text.