Flake-resistant multilayer thin-film electrodes and electrolytic cells incorporating same
OwnerGeorge H. Mileyinventor
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Abstract
Described are preferred multilayer, thin-film electrodes (11) that have improved resistance to flaking or cracking under conditions of operation. Also described are electrolytic cells (17) incorporating such electrodes (11), and methods for selecting electrode materials to facilitate reaction rates, energy production, and/or to shift the average mass number of transmuted products to lighter or heavier values. Preferred electrodes (11) have a plurality of thin-film conductive layers (14) supported on generally concave surfaces (13).
Claims27
A concave-surface conductive article for use as an electrode, comprising an electrode substrate having at least one concave surface, and at least one thin-film conductive layer coated on said concave surface;
- wherein said layer includes a metal selected from Table 1;
- and
- wherein an outer surface of an outermost one of said thin conductive layers is coated with a hydrogen diffusion barrier.
A concave-surface conductive article for use as an electrode, comprising an electrode substrate having at least one concave surface and a plurality of thin-film conductive layers coated on said concave surface, wherein said layers include alternating layers of two differing conductive materials selected from Table 1.
A concave-surface conductive article for use as an electrode, comprising an electrode substrate having at least one concave surface and at least one thin-film conductive layer coated on said concave surface, wherein said conductive article is a pellet.
A concave-surface conductive article for use as an electrode, comprising an electrode substrate having at least one concave surface and at least one thin-film conductive layer coated on said concave surface, wherein said conductive article is a rod.
A concave-surface conductive article for use as an electrode, comprising an electrode substrate having at least one concave surface and at least one thin-film conductive layer coated on said concave surface, wherein said conductive article is a fiber.
An electrolytic cell, comprising first and second electrodes, at least one of which includes a conductive article having an electrode substrate with at least one concave surface, and at least one thin conductive layer coated on said concave surface.
A flake-resistant thin-film layer electrode for use in an electrolytic cell, comprising:
- an electrode substrate including a surface;
- and
- at least one thin conductive layer coated on said concave surface which is subjected to compressive force upon expansion of said thin conductive layer.
A flake-resistant thin-film electrode for use in an electrolytic cell, comprising:
- an electrode substrate;
- a plurality of thin-film conductive layers coated on said electrode substrate;
- and
- expansion gaps provided in said thin conductive layers so as to reduce flaking or cracking of the thin conductive layers when expanded.
An electrode for an electrolytic cell, comprising alternating thin-film layers of two conductive materials, said conductive materials having a difference in Fermi energy levels of at least about 1 eV and substantial solubility and diffusivity for hydrogenous ions;
- said two conductive materials further providing an interface at which substantially no interdiffusion occurs.
An electrode for an electrolytic cell, comprising a substrate and a first thin-film conductive layer on the substrate, the substrate and first thin film conductive layer having a difference in Fermi energy level of at least about 1 eV.
An electrode for an electrolytic cell, comprising a substrate and thin conductive layers with an outer thin coating selected to serve as a hydrogen diffusion barrier and have a difference in Fermi energy level relative to the underlying thin conductive layer of at least about 1 eV.
An electrolytic cell which comprises a first electrode including a bed of pellets, each having a thin-film conductive layer, said cell also having means for increasing on average the electric field strength on said thin-film conductive layer.
An electrolytic cell including an anode, a bed of pellets each having a thin-film conductive layer, a first cathode member in electrical contact with an end of said bed of pellets, and a second cathode member in contact with said bed of pellets at a position intermediate to said first cathode member and said anode.
A conductive pellet for use in a cathode in an electrolytic cell, comprising a substrate, a first layer including a metal selected from one of the Fermi level groups in Table I, and a second layer adjacent the first layer including a metal selected from a different Fermi level group in Table I.
Dependencies are inferred from the claim text.