Process for the preparation of unsaturated ketones
AssigneeDegussa AG
InventorsNongyuan Shi, Bernd Drapal, Steffen Krill, Markus Julino, Klaus Huthmacher
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Abstract
A process for the preparation of β,γ,δ-unsaturated ketones and/or α,β,γ,δ-unsaturated ketones by the reaction of an unsaturated alcohol with an enol ether or mixture of enol ethers, with formation of ketals as a by-product, at temperatures of from 50° C. to 200° C., in the presence of an acid catalyst, whereby one or all of the reagents is/are heated to the reaction temperature of from 50° C. to 200° C. before the acid catalyst is added.
Claims20
A process for preparing one or more β,γ,δ-unsaturated ketones and/or one or more α,β,γ,δ-unsaturated ketones, said process comprising
- reacting at least one unsaturated alcohol with at least one enol ether in the presence of an acid catalyst at a temperature of from 50° C. to 200° C., to form said unsaturated ketones and one or more ketals,
- wherein said unsaturated alcohol and/or said enol ether is heated to a reaction temperature of from 50° C. to 200° C. before said acid catalyst is added.
Dependencies are inferred from the claim text.