Process for the preparation of alkyl 3-oxo-2-pentyl-1-cyclopenteneacetates
AssigneeFirmenich SA
InventorsKhushrav Crawford, Valentin Rautenstrauch, Arnoldus Uijttewaal
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AssigneeFirmenich SA
InventorsKhushrav Crawford, Valentin Rautenstrauch, Arnoldus Uijttewaal
Estimating the term…
The present invention discloses a process for the preparation of a compound according to formula wherein R1 is a C3-C7 alkyl group and R2 is a C1 to C4, linear or branched, alkyl radical, more preferably a methyl group, characterized in that the process includes the isomerisation of an epoxide of formula wherein R1 and R2 have the meaning given in formula (I), in the presence of an acidic isomerisation agent, a thermal treatment or a combination thereof. The process according to the invention allows the preparation of the cyclopentenyl compounds of formula (I) on an industrial scale. The compounds are important starting products for the production of appreciated perfuming ingredients in particular methyl dihydrojasmonates.
A process for the preparation of a compound according to formula
A compound of formula
A compound of formula
Dependencies are inferred from the claim text.