Multidentate sulfur-containing ligands
AssigneeUniversity of Kentucky Research Foundation
InventorsDavid A. Atwood, Brock S. Howerton, Matthew Matlock
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AssigneeUniversity of Kentucky Research Foundation
InventorsDavid A. Atwood, Brock S. Howerton, Matthew Matlock
Estimating the term…
Novel sulfur-containing ligands for binding of heavy metals are disclosed. The ligands incorporate a central ring structure and pendant alkyl-thiol chains. The ligands are of the general structure: where n is an integer from 1-4, and X is selected from the group consisting of hydrogen, lithium, sodium, potassium, rubidium, cesium, and francium. The ligands of the present invention are suitable for binding any metal in or capable of being placed in a positive oxidation state, such as cadmium, lead, nickel, zinc, mercury, copper, and the like. Additionally, methods for removal of heavy metals from various substances are disclosed, comprising separating selected heavy metals from selected substances by contacting the substances with an effective amount of the novel sulfur-containing chelate ligands for a sufficient time to form stable, irreversible ligand-metal precipitates, and removing such precipitates.
A chemical compound, comprising:
A chemical compound, comprising:
A chemical compound, comprising:
A method of removing metal from a starting material selected from the group consisting of a fluid, a solid, or any mixture thereof, comprising binding said metal in an effective amount of chelate ligand having a chemical formula:
A method of removing metal from a starting material selected from the group consisting of a fluid, a solid, or any mixture thereof, comprising binding said metal in an effective amount of a chelate ligand having a chemical formula:
A method of removing metal from a starting material selected from the group consisting of a fluid, a solid, or any mixture thereof, comprising binding said metal in an effective amount of a chelate ligand having a chemical formula:
A method of removing metal from water, comprising:
A method of removal of metal from water, comprising:
A method of removal of metal from water, comprising:
A method of acid mine drainage treatment, comprising:
A method of acid mine drainage treatment, comprising:
A method of acid mine drainage treatment, comprising:
A method of treatment of soil containing metal, comprising:
A method of treatment of soil containing metal, comprising:
A method of treatment of soil containing metal, comprising:
Dependencies are inferred from the claim text.