A single crystal silicon wafer having two major, generally parallel surfaces, one of which is the front surface of the wafer and the other of which is the back surface of the wafer, a central plane between the front and back surfaces, a circumferential edge joining the front and back surfaces, a front surface layer which comprises a first region of the wafer between the front surface and a distance, D1, of at least about 10 micrometers as measured from the front surface and toward the central plane, a back surface layer which comprises a second region of the wafer between the back surface and a distance D2, of at least about 10 micrometers as measured from the back surface and toward the central plane and a bulk layer which comprises a third region of the wafer between the front surface layer and the back surface layer, the wafer being characterized in that;
- the wafer has an asymmetrical vacancy concentration profile in the cooled wafer in which a maximum concentration is located between the central plane and the back surface layer, the vacancy concentration generally increasing from the front surface to the region of maximum concentration and generally decreasing from the region of maximum concentration to the back surface and the difference in the concentration of vacancies in the front surface layer, the back surface layer and the bulk layer being such that a thermal treatment at a temperature in excess of 750° C., is capable of forming in the wafer a denuded zone in the front surface layer and in the back surface layer and oxygen clusters or precipitates in the bulk zone with the concentration of the oxygen clusters or precipitates in the bulk layer being primarily dependant upon the concentration of vacancies.