Mitigation and gasification of coke deposits
AssigneeExxonMobil Research and Engineering Company
InventorsSimon Robert Kelemen, Michael Siskin, Glen Edward Phillips, Nicholas Charles Nahas
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Abstract
A method for removing or reducing coke deposits in a refinery reactor unit utilizing a reactant gas, preferably steam, and catalyst.
Claims27
A method for removing or reducing coke deposits in a reactor unit selected from the group consisting of FCC, fluid coking, FLEXICOKING, and delayed coking units, said method comprising catalytically gasifying said coke deposits by (a) optionally ceasing hydrocarbon feed to said unit, (b) in the substantial absence of a reactant gas in said reactor treating said coke deposits with a catalyst as a solution to coat and/or impregnate said coke deposits with said catalyst being effective in converting coke to a gaseous product comprising hydrogen and carbon monoxide, (c) contacting said coke deposits with said reactant gas comprising substantially steam, in the substantial absence of oxygen, at a temperature of from about 500° C. to about 700° C. for a time sufficient to convert a portion of said coke deposits to a gaseous product comprising substantially carbon monoxide and hydrogen.
A method for reducing coke deposits in a reactor unit selected from the group consisting of FCC, fluid coking, FLEXICOKING, and delayed coking units, said method comprising:
- ceasing hydrocarbon feed to said unit,
- in the substantial absence of a reactant gas in said reactor treating said coke deposits with an effective amount of a decoking catalyst as a solution to coat and/or impregnate said coke deposits with said decoking catalyst,
- contacting said treated coke deposits with said reactant gas comprising substantially steam at an effective temperature and for a time sufficient for an effective reduction of said treated coke deposits to a gaseous product comprising substantially carbon monoxide and hydrogen.
Dependencies are inferred from the claim text.