Clarified thermoplastics exhibiting very high nucleation efficacy
AssigneeMilliken & Company
InventorXiaodong Edward Zhao
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AssigneeMilliken & Company
InventorXiaodong Edward Zhao
Estimating the term…
Certain thermoplastic additives (combinations of clarifying and nucleating compounds) that induce simultaneously low clarity and high nucleation efficacy are provided. Such additives include combinations of certain bicyclic salts (which by themselves induce very high nucleation efficacy) and thermoplastic clarifying agents, including certain dibenzylidene sorbitol acetals and derivatives (hereinafter collectively referred to as “DBSs”)(which alone provide very low haze measurements and thus highly desirable clarity characteristics). In comparison, other types of standard thermoplastic nucleators, such as sodium benzoate and sodium 2,2′-methylene-bis-(4,6-di-tert-butylphenyl) phosphate provide relatively high peak crystallization temperatures, but do not combine synergistically with clarifiers, such as DBSs, to provide the same results as for the inventive combination of bicyclic salts and DBSs. Thermoplastic compositions as well as thermoplastic additive packages comprising such inventive nucleator compounds, as well as methods of producing polypropylene compositions and articles made therefrom, are also contemplated within this invention.
An additive composition of compounds that provides both nucleating and clarifying characteristics within thermoplastics, wherein said additive composition comprises at least two different compounds, a first compound being a saturated bicyclic carboxylic acid salt cyclic compound that induces nucleation within polypropylene and a second compound being an alditol-based polypropylene clarifying compound, wherein said additive composition induces a peak crystallization temperature of at least 125° C. and simultaneously a haze measurement of at most 20% for a test homopolymer polypropylene formulation comprising said nucleating agent, wherein the unnucleated test homopolymer propylene exhibits a density of about 0.9 g/cc, a melt flow of about 12 g/10 mm, a Rockwell Hardness (R scale) of about 90, a tensile strength of about 4,931 psi, an elongation at yield of about 10%, a flexural modulus of about 203 ksi, an Izod impact strength of about 0.67 ft-lb/in, and a deflection temperature at 0.46 mPa of about 93°, and wherein said formulation comprising said combination is extruded then molded into plaques having dimensions of about 51 mm×76 mm×1.27 mm, wherein said peak crystallization temperature is measured by differential scanning calorimetry in accordance with a modified ASTM Test Method D3417-99 at heating and cooling rates of 20° C./minute, wherein said haze measurements are performed in accordance with ASTM Standard Test Method D1003-61, and wherein the total amount of said additive composition present within said test homopolymer is at most 0.35% by weight.
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